Effect of ceramics/polymer heterointerface on dielectric property of self-assembled BaTiO3/poly-L-lactic acid composite materials

Mariko Takeda*, Kentaro Yoshino, Akira Ito, Makoto Tanimura, Yasuhide Inoue, Yasumasa Koyama, Fumio Munakata

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

2 Citations (Scopus)

Abstract

The dispersion state of barium titanate (BT) particle groups in self-assembled BT/poly-L-lactic-acid (PLLA) composites prepared under different fabrication conditions was investigated. In particular, the BT/PLLA/BT heterointerface in the BT aggregates by the self-assembly process was analyzed and the effect of the BT/PLLA/ BT heterointerface and the BT/BT interface on the dielectric properties of BT/PLLA composites were investigated. BT/PLLA composites were fabricated by adding BT particles and BT granules with low and high-speed kneading conditions. The volume fraction of BT in composites varied from 5 to 20 vol.%. The BT aggregates having a BT/PLLA/BT heterointerface were formed under the low-speed kneading condition and the BT agglomerates having a BT/BT interface were formed under the high-speed kneading condition within the self-assembly process. The tan ¤ of the BT/PLLA composite of self-assembled BT aggregates having the BT/PLLA/ BT heterointerface was lower than that of the BT granules having the BT/BT interface. The dielectric constant (¾¤) of the self-assembled composite was increased by growing an average secondary particle area of BT fillers. In contrast, the average secondary particle area of BT granules was increased, as compared with 5 vol.% of BT. However, the change in ¾¤ was saturated. The slopes of the change in the ¾¤ depending on the secondary particle area of BT fillers were different between the self-assembled BT aggregates having the BT/PLLA/BT heterointerface and the BT granules having the BT/BT interface. Thus, it was suggested that it was an important role in improving the dielectric properties to form ceramic secondary particle groups having the ceramics/polymer/ceramics heterointerface by the self-assembly process.

Original languageEnglish
Pages (from-to)135-142
Number of pages8
JournalJournal of the Ceramic Society of Japan
Volume129
Issue number3
DOIs
Publication statusPublished - 2021 Mar

Keywords

  • BaTiO/PLLA
  • Ceramics/polymer heterointerface
  • Dielectric property Self-assembly
  • Polymer composite material

ASJC Scopus subject areas

  • Ceramics and Composites
  • Chemistry(all)
  • Condensed Matter Physics
  • Materials Chemistry

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