Effect of curing temperature and phosphoric acid on corrosion resistance of mannich-modified phenolic resin on galvanized steel surface

Ryosuke Sako, Jun'Ichi Sakai

    Research output: Contribution to journalArticle

    2 Citations (Scopus)

    Abstract

    Phenolic resin modified by Mannich reaction with an amine was investigated as an alternative to chromate on galvanized steel surface. The corrosion resistance of the resin coating was improved with increasing of the curing temperature, furthermore also improved by addition of phosphoric acid into the resin solution. Surface free energy measurement, infrared absorption analysis, GDS analysis, XPS analysis, etc. were carried out in order to clarify the effect of curing temperature and the addition of phosphoric acid; as the result some findings were obtained. The coating film became more hydrophobic, because cross-linking reaction proceeded with the elimination of the diethanolamine, which is the amine for modification, in curing over 160... It was revealed that the phosphoric acid included in the resin coating has been eliminated together with diethanolamine during the cross-linking reaction and it has diffused through the resin coating to form an insoluble phosphate layer at the interface between resin coating and galvanized steel. The electrochemical measurement clarified that the insoluble phosphate layer suppressed cathode reaction. reduction reaction of dissolved oxygen.

    Original languageEnglish
    Pages (from-to)17-24
    Number of pages8
    JournalZairyo to Kankyo/ Corrosion Engineering
    Volume63
    Issue number1
    Publication statusPublished - 2014

    Fingerprint

    Phenolic resins
    Steel
    Phosphoric acid
    diethanolamine
    Corrosion resistance
    Curing
    Resins
    Coatings
    Amines
    Phosphates
    Temperature
    Chromates
    Electric power measurement
    Infrared absorption
    Dissolved oxygen
    Free energy
    Cathodes
    X ray photoelectron spectroscopy
    phosphoric acid
    phenol-formaldehyde resin

    Keywords

    • Chromium free
    • Corrosion resistance
    • Film formation
    • Galvanized steel
    • Mannich reaction
    • Mechanism
    • Phenolic resin
    • Phosphoric acid
    • Surface treatment

    ASJC Scopus subject areas

    • Electrochemistry
    • Materials Chemistry
    • Metals and Alloys
    • Surfaces, Coatings and Films

    Cite this

    Effect of curing temperature and phosphoric acid on corrosion resistance of mannich-modified phenolic resin on galvanized steel surface. / Sako, Ryosuke; Sakai, Jun'Ichi.

    In: Zairyo to Kankyo/ Corrosion Engineering, Vol. 63, No. 1, 2014, p. 17-24.

    Research output: Contribution to journalArticle

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    abstract = "Phenolic resin modified by Mannich reaction with an amine was investigated as an alternative to chromate on galvanized steel surface. The corrosion resistance of the resin coating was improved with increasing of the curing temperature, furthermore also improved by addition of phosphoric acid into the resin solution. Surface free energy measurement, infrared absorption analysis, GDS analysis, XPS analysis, etc. were carried out in order to clarify the effect of curing temperature and the addition of phosphoric acid; as the result some findings were obtained. The coating film became more hydrophobic, because cross-linking reaction proceeded with the elimination of the diethanolamine, which is the amine for modification, in curing over 160... It was revealed that the phosphoric acid included in the resin coating has been eliminated together with diethanolamine during the cross-linking reaction and it has diffused through the resin coating to form an insoluble phosphate layer at the interface between resin coating and galvanized steel. The electrochemical measurement clarified that the insoluble phosphate layer suppressed cathode reaction. reduction reaction of dissolved oxygen.",
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