Abstract
Ni/perovskite-type oxide catalyst (Ni/La<inf>0.7</inf>Sr<inf>0.3</inf>AlO<inf>2.85</inf>: LSAO) shows high catalytic activity and low carbon formation during the steam reforming of aromatic hydrocarbons because of the high mobility of lattice oxygen in the support. The reaction mechanisms of the catalyst were investigated by characterizations and catalytic activity tests for steam reforming of various hydrocarbons including toluene, methylcyclohexane, and n-heptane. The catalytic performance was affected by the reactant structure, as revealed by Arrhenius plots and FT-IR analyses. Adsorption state and stability of reaction intermediates were very important factors in the catalytic activity for steam reforming.
| Original language | English |
|---|---|
| Pages (from-to) | 86-96 |
| Number of pages | 11 |
| Journal | Journal of the Japan Petroleum Institute |
| Volume | 58 |
| Issue number | 2 |
| DOIs | |
| Publication status | Published - 2015 |
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Keywords
- Adsorption state
- Hydrocarbon steam reforming
- Hydrogen production
- Nickel catalyst
- SSITKA
ASJC Scopus subject areas
- Energy Engineering and Power Technology
- Fuel Technology
Cite this
Effect of hydrocarbon structure on steam reforming over Ni/perovskite catalyst. / Higo, Takuma; Hashimoto, Takashi; Mukai, Daiki; Nagatake, Satoshi; Ogo, Shuhei; Sugiura, Yukihiro; Sekine, Yasushi.
In: Journal of the Japan Petroleum Institute, Vol. 58, No. 2, 2015, p. 86-96.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Effect of hydrocarbon structure on steam reforming over Ni/perovskite catalyst
AU - Higo, Takuma
AU - Hashimoto, Takashi
AU - Mukai, Daiki
AU - Nagatake, Satoshi
AU - Ogo, Shuhei
AU - Sugiura, Yukihiro
AU - Sekine, Yasushi
PY - 2015
Y1 - 2015
N2 - Ni/perovskite-type oxide catalyst (Ni/La0.7Sr0.3AlO2.85: LSAO) shows high catalytic activity and low carbon formation during the steam reforming of aromatic hydrocarbons because of the high mobility of lattice oxygen in the support. The reaction mechanisms of the catalyst were investigated by characterizations and catalytic activity tests for steam reforming of various hydrocarbons including toluene, methylcyclohexane, and n-heptane. The catalytic performance was affected by the reactant structure, as revealed by Arrhenius plots and FT-IR analyses. Adsorption state and stability of reaction intermediates were very important factors in the catalytic activity for steam reforming.
AB - Ni/perovskite-type oxide catalyst (Ni/La0.7Sr0.3AlO2.85: LSAO) shows high catalytic activity and low carbon formation during the steam reforming of aromatic hydrocarbons because of the high mobility of lattice oxygen in the support. The reaction mechanisms of the catalyst were investigated by characterizations and catalytic activity tests for steam reforming of various hydrocarbons including toluene, methylcyclohexane, and n-heptane. The catalytic performance was affected by the reactant structure, as revealed by Arrhenius plots and FT-IR analyses. Adsorption state and stability of reaction intermediates were very important factors in the catalytic activity for steam reforming.
KW - Adsorption state
KW - Hydrocarbon steam reforming
KW - Hydrogen production
KW - Nickel catalyst
KW - SSITKA
UR - http://www.scopus.com/inward/record.url?scp=84929497798&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=84929497798&partnerID=8YFLogxK
U2 - 10.1627/jpi.58.86
DO - 10.1627/jpi.58.86
M3 - Article
AN - SCOPUS:84929497798
VL - 58
SP - 86
EP - 96
JO - Journal of the Japan Petroleum Institute
JF - Journal of the Japan Petroleum Institute
SN - 1346-8804
IS - 2
ER -