Effect of structural randomness on the frontier states of polysilane

Kyozaburo Takeda; Nobuo Matsumoto

doi:10.1088/0022-3719/18/33/003

Effect of structural randomness on the frontier states of polysilane

Kyozaburo Takeda, Nobuo Matsumoto

Research output: Contribution to journal › Article › peer-review

17 Citations (Scopus)

Abstract

The effect of simple structural randomness, such as stretching branching and surrounding, on the electronic structure of polysilane is investigated using molecular orbital calculation. The frontier orbital (homo and lumo) states consist mainly of skeleton Si. The fluctuation in the frontier orbital states due to such randomness are found to be quite small. Moreover, tailing of the resulting gap states into the energy gap is negligible.

Original language	English
Pages (from-to)	6121-6133
Number of pages	13
Journal	Journal of Physics C: Solid State Physics
Volume	18
Issue number	33
DOIs	https://doi.org/10.1088/0022-3719/18/33/003
Publication status	Published - 1985 Nov 30
Externally published	Yes

ASJC Scopus subject areas

Condensed Matter Physics
Engineering(all)
Physics and Astronomy(all)

Access to Document

10.1088/0022-3719/18/33/003

Cite this

@article{9aec8811e5104373aa5e31204ea9073b,

title = "Effect of structural randomness on the frontier states of polysilane",

abstract = "The effect of simple structural randomness, such as stretching branching and surrounding, on the electronic structure of polysilane is investigated using molecular orbital calculation. The frontier orbital (homo and lumo) states consist mainly of skeleton Si. The fluctuation in the frontier orbital states due to such randomness are found to be quite small. Moreover, tailing of the resulting gap states into the energy gap is negligible.",

author = "Kyozaburo Takeda and Nobuo Matsumoto",

year = "1985",

month = nov,

day = "30",

doi = "10.1088/0022-3719/18/33/003",

language = "English",

volume = "18",

pages = "6121--6133",

journal = "Journal of Physics Condensed Matter",

issn = "0953-8984",

publisher = "IOP Publishing Ltd.",

number = "33",

}

TY - JOUR

T1 - Effect of structural randomness on the frontier states of polysilane

AU - Takeda, Kyozaburo

AU - Matsumoto, Nobuo

PY - 1985/11/30

Y1 - 1985/11/30

N2 - The effect of simple structural randomness, such as stretching branching and surrounding, on the electronic structure of polysilane is investigated using molecular orbital calculation. The frontier orbital (homo and lumo) states consist mainly of skeleton Si. The fluctuation in the frontier orbital states due to such randomness are found to be quite small. Moreover, tailing of the resulting gap states into the energy gap is negligible.

AB - The effect of simple structural randomness, such as stretching branching and surrounding, on the electronic structure of polysilane is investigated using molecular orbital calculation. The frontier orbital (homo and lumo) states consist mainly of skeleton Si. The fluctuation in the frontier orbital states due to such randomness are found to be quite small. Moreover, tailing of the resulting gap states into the energy gap is negligible.

UR - http://www.scopus.com/inward/record.url?scp=14344272246&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=14344272246&partnerID=8YFLogxK

U2 - 10.1088/0022-3719/18/33/003

DO - 10.1088/0022-3719/18/33/003

M3 - Article

AN - SCOPUS:14344272246

SN - 0953-8984

VL - 18

SP - 6121

EP - 6133

JO - Journal of Physics Condensed Matter

JF - Journal of Physics Condensed Matter

IS - 33

ER -

Effect of structural randomness on the frontier states of polysilane

Abstract

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this