Abstract
The aim of this work has been to investigate the effect of the modification of Ag surface by simultaneous underpotential deposition (upd) of Pb and Tl on the electroreduction of Cr(OH//2)Cl**2** plus . The upd layers of Pb and Tl inhibit the electroreduction of Cr(OH//2)//5Cl**2** plus and the effect is a linear function of the upd metal coverage. The most likely explanation is that the interaction of the halide as a bridging species with the upd covered surface is less favorable than that with the substrate alone.
| Original language | English |
|---|---|
| Pages | 412-414 |
| Number of pages | 3 |
| Publication status | Published - 1984 Dec 1 |
| Externally published | Yes |
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ASJC Scopus subject areas
- Engineering(all)
Cite this
EFFECT OF UNDERPOTENTIAL DEPOSITION ON THE KINETICS OF THE CHROMOUS-CHROMIC COUPLE. / Wu, C. D.; Calvo, E. J.; Scherson, Daniel Alberto; Reid, M.; Yeager, E.
1984. 412-414.Research output: Contribution to conference › Paper
}
TY - CONF
T1 - EFFECT OF UNDERPOTENTIAL DEPOSITION ON THE KINETICS OF THE CHROMOUS-CHROMIC COUPLE.
AU - Wu, C. D.
AU - Calvo, E. J.
AU - Scherson, Daniel Alberto
AU - Reid, M.
AU - Yeager, E.
PY - 1984/12/1
Y1 - 1984/12/1
N2 - The aim of this work has been to investigate the effect of the modification of Ag surface by simultaneous underpotential deposition (upd) of Pb and Tl on the electroreduction of Cr(OH//2)Cl**2** plus . The upd layers of Pb and Tl inhibit the electroreduction of Cr(OH//2)//5Cl**2** plus and the effect is a linear function of the upd metal coverage. The most likely explanation is that the interaction of the halide as a bridging species with the upd covered surface is less favorable than that with the substrate alone.
AB - The aim of this work has been to investigate the effect of the modification of Ag surface by simultaneous underpotential deposition (upd) of Pb and Tl on the electroreduction of Cr(OH//2)Cl**2** plus . The upd layers of Pb and Tl inhibit the electroreduction of Cr(OH//2)//5Cl**2** plus and the effect is a linear function of the upd metal coverage. The most likely explanation is that the interaction of the halide as a bridging species with the upd covered surface is less favorable than that with the substrate alone.
UR - http://www.scopus.com/inward/record.url?scp=0021567373&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=0021567373&partnerID=8YFLogxK
M3 - Paper
SP - 412
EP - 414
ER -