EFFECT OF UNDERPOTENTIAL DEPOSITION ON THE KINETICS OF THE CHROMOUS-CHROMIC COUPLE.

C. D. Wu, E. J. Calvo, Daniel Alberto Scherson, M. Reid, E. Yeager

Research output: Contribution to conferencePaper

Abstract

The aim of this work has been to investigate the effect of the modification of Ag surface by simultaneous underpotential deposition (upd) of Pb and Tl on the electroreduction of Cr(OH//2)Cl**2** plus . The upd layers of Pb and Tl inhibit the electroreduction of Cr(OH//2)//5Cl**2** plus and the effect is a linear function of the upd metal coverage. The most likely explanation is that the interaction of the halide as a bridging species with the upd covered surface is less favorable than that with the substrate alone.

Original languageEnglish
Pages412-414
Number of pages3
Publication statusPublished - 1984 Dec 1
Externally publishedYes

Fingerprint

Kinetics
Substrates
Metals

ASJC Scopus subject areas

  • Engineering(all)

Cite this

EFFECT OF UNDERPOTENTIAL DEPOSITION ON THE KINETICS OF THE CHROMOUS-CHROMIC COUPLE. / Wu, C. D.; Calvo, E. J.; Scherson, Daniel Alberto; Reid, M.; Yeager, E.

1984. 412-414.

Research output: Contribution to conferencePaper

@conference{2aeb2e2745a74960b682887ab97de458,
title = "EFFECT OF UNDERPOTENTIAL DEPOSITION ON THE KINETICS OF THE CHROMOUS-CHROMIC COUPLE.",
abstract = "The aim of this work has been to investigate the effect of the modification of Ag surface by simultaneous underpotential deposition (upd) of Pb and Tl on the electroreduction of Cr(OH//2)Cl**2** plus . The upd layers of Pb and Tl inhibit the electroreduction of Cr(OH//2)//5Cl**2** plus and the effect is a linear function of the upd metal coverage. The most likely explanation is that the interaction of the halide as a bridging species with the upd covered surface is less favorable than that with the substrate alone.",
author = "Wu, {C. D.} and Calvo, {E. J.} and Scherson, {Daniel Alberto} and M. Reid and E. Yeager",
year = "1984",
month = "12",
day = "1",
language = "English",
pages = "412--414",

}

TY - CONF

T1 - EFFECT OF UNDERPOTENTIAL DEPOSITION ON THE KINETICS OF THE CHROMOUS-CHROMIC COUPLE.

AU - Wu, C. D.

AU - Calvo, E. J.

AU - Scherson, Daniel Alberto

AU - Reid, M.

AU - Yeager, E.

PY - 1984/12/1

Y1 - 1984/12/1

N2 - The aim of this work has been to investigate the effect of the modification of Ag surface by simultaneous underpotential deposition (upd) of Pb and Tl on the electroreduction of Cr(OH//2)Cl**2** plus . The upd layers of Pb and Tl inhibit the electroreduction of Cr(OH//2)//5Cl**2** plus and the effect is a linear function of the upd metal coverage. The most likely explanation is that the interaction of the halide as a bridging species with the upd covered surface is less favorable than that with the substrate alone.

AB - The aim of this work has been to investigate the effect of the modification of Ag surface by simultaneous underpotential deposition (upd) of Pb and Tl on the electroreduction of Cr(OH//2)Cl**2** plus . The upd layers of Pb and Tl inhibit the electroreduction of Cr(OH//2)//5Cl**2** plus and the effect is a linear function of the upd metal coverage. The most likely explanation is that the interaction of the halide as a bridging species with the upd covered surface is less favorable than that with the substrate alone.

UR - http://www.scopus.com/inward/record.url?scp=0021567373&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=0021567373&partnerID=8YFLogxK

M3 - Paper

SP - 412

EP - 414

ER -