EFFECT OF UNDERPOTENTIAL DEPOSITION ON THE KINETICS OF THE CHROMOUS-CHROMIC COUPLE.

C. D. Wu; E. J. Calvo; Daniel Alberto Scherson; M. Reid; E. Yeager

EFFECT OF UNDERPOTENTIAL DEPOSITION ON THE KINETICS OF THE CHROMOUS-CHROMIC COUPLE.

C. D. Wu, E. J. Calvo, Daniel Alberto Scherson, M. Reid, E. Yeager

Research output: Contribution to conference › Paper › peer-review

Abstract

The aim of this work has been to investigate the effect of the modification of Ag surface by simultaneous underpotential deposition (upd) of Pb and Tl on the electroreduction of Cr(OH//2)Cl**2** plus . The upd layers of Pb and Tl inhibit the electroreduction of Cr(OH//2)//5Cl**2** plus and the effect is a linear function of the upd metal coverage. The most likely explanation is that the interaction of the halide as a bridging species with the upd covered surface is less favorable than that with the substrate alone.

Original language	English
Pages	412-414
Number of pages	3
Publication status	Published - 1984 Dec 1
Externally published	Yes

ASJC Scopus subject areas

Engineering(all)

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title = "EFFECT OF UNDERPOTENTIAL DEPOSITION ON THE KINETICS OF THE CHROMOUS-CHROMIC COUPLE.",

abstract = "The aim of this work has been to investigate the effect of the modification of Ag surface by simultaneous underpotential deposition (upd) of Pb and Tl on the electroreduction of Cr(OH//2)Cl**2** plus . The upd layers of Pb and Tl inhibit the electroreduction of Cr(OH//2)//5Cl**2** plus and the effect is a linear function of the upd metal coverage. The most likely explanation is that the interaction of the halide as a bridging species with the upd covered surface is less favorable than that with the substrate alone.",

author = "Wu, {C. D.} and Calvo, {E. J.} and Scherson, {Daniel Alberto} and M. Reid and E. Yeager",

year = "1984",

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pages = "412--414",

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T1 - EFFECT OF UNDERPOTENTIAL DEPOSITION ON THE KINETICS OF THE CHROMOUS-CHROMIC COUPLE.

AU - Wu, C. D.

AU - Calvo, E. J.

AU - Scherson, Daniel Alberto

AU - Reid, M.

AU - Yeager, E.

PY - 1984/12/1

Y1 - 1984/12/1

N2 - The aim of this work has been to investigate the effect of the modification of Ag surface by simultaneous underpotential deposition (upd) of Pb and Tl on the electroreduction of Cr(OH//2)Cl**2** plus . The upd layers of Pb and Tl inhibit the electroreduction of Cr(OH//2)//5Cl**2** plus and the effect is a linear function of the upd metal coverage. The most likely explanation is that the interaction of the halide as a bridging species with the upd covered surface is less favorable than that with the substrate alone.

AB - The aim of this work has been to investigate the effect of the modification of Ag surface by simultaneous underpotential deposition (upd) of Pb and Tl on the electroreduction of Cr(OH//2)Cl**2** plus . The upd layers of Pb and Tl inhibit the electroreduction of Cr(OH//2)//5Cl**2** plus and the effect is a linear function of the upd metal coverage. The most likely explanation is that the interaction of the halide as a bridging species with the upd covered surface is less favorable than that with the substrate alone.

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