Effective luminescence quenching of tris(2,2-bipyridine)ruthenium(II) by methylviologen on clay by the aid of poly(vinylpyrrolidone)

Norishige Kakegawa, Makoto Ogawa

Research output: Contribution to journalArticle

17 Citations (Scopus)

Abstract

Electron-transfer quenching of tris(2,2-bipyridine)ruthenium(II) by methylviologen in an aqueous suspension of clay in the presence of poly(vinylpyrrolidone) was investigated. The quenching behavior of the excited tris(2,2-bipyridine)ruthenium(II) on clay by the coadsorbed methylviologen indicated the homogeneous distribution of the adsorbed dyes. The quenching rate was high when the clay with larger particle size was used as the host. The adsorption of poly(vinylpyrrolidone) on clay resulted in the coadsorption of the tris(2,2-bipyridine)ruthenium(II) and methylviologen without segregation.

Original languageEnglish
Pages (from-to)7004-7009
Number of pages6
JournalLangmuir
Volume20
Issue number17
DOIs
Publication statusPublished - 2004 Aug 17

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Colloid and Surface Chemistry

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