Effects of potential on hydrogen absorption and desorption behaviors of titanium in neutral fluoride solutions

Katsutoshi Takashima, Ken'ichi Yokoyama, Kenzo Asaoka, Jun'ichi Sakai

    Research output: Contribution to journalArticle

    8 Citations (Scopus)

    Abstract

    The effects of potential on the hydrogen absorption and desorption of commercial pure titanium immersed in neutral 2.0% and 0.2% NaF solutions for 24 h have been investigated by hydrogen thermal desorption analysis. Hydrogen absorption occurs in both solutions under less noble potentials than -1.2 V versus a saturated calomel electrode. The amount of absorbed hydrogen increases with decreasing applied potential. Under the same applied potential, the amount of hydrogen absorbed in the 2.0% NaF solution is larger than that in the 0.2% NaF solution. Hydrogen thermal desorption is observed in the temperature range from 250-300 to 700 °C. For the 2.0% NaF solution, compared with the 0.2% NaF solution, the amount of hydrogen desorbed in the high temperature range is large. The hydrogen desorption behavior for neutral NaF solutions under the applied potential is not necessarily consistent with that for acidulated phosphate fluoride solutions without the applied potential reported previously.

    Original languageEnglish
    Pages (from-to)203-207
    Number of pages5
    JournalJournal of Alloys and Compounds
    Volume431
    Issue number1-2
    DOIs
    Publication statusPublished - 2007 Apr 4

    Fingerprint

    Titanium
    Fluorides
    Hydrogen
    Desorption
    Thermal desorption
    Acidulated Phosphate Fluoride
    Phosphates
    Temperature
    Electrodes

    Keywords

    • Corrosion
    • Fluoride
    • Hydrogen embrittlement
    • Thermal desorption analysis
    • Titanium

    ASJC Scopus subject areas

    • Metals and Alloys

    Cite this

    Effects of potential on hydrogen absorption and desorption behaviors of titanium in neutral fluoride solutions. / Takashima, Katsutoshi; Yokoyama, Ken'ichi; Asaoka, Kenzo; Sakai, Jun'ichi.

    In: Journal of Alloys and Compounds, Vol. 431, No. 1-2, 04.04.2007, p. 203-207.

    Research output: Contribution to journalArticle

    Takashima, Katsutoshi ; Yokoyama, Ken'ichi ; Asaoka, Kenzo ; Sakai, Jun'ichi. / Effects of potential on hydrogen absorption and desorption behaviors of titanium in neutral fluoride solutions. In: Journal of Alloys and Compounds. 2007 ; Vol. 431, No. 1-2. pp. 203-207.
    @article{a839c3f7a8de49a695e812798a68cc62,
    title = "Effects of potential on hydrogen absorption and desorption behaviors of titanium in neutral fluoride solutions",
    abstract = "The effects of potential on the hydrogen absorption and desorption of commercial pure titanium immersed in neutral 2.0{\%} and 0.2{\%} NaF solutions for 24 h have been investigated by hydrogen thermal desorption analysis. Hydrogen absorption occurs in both solutions under less noble potentials than -1.2 V versus a saturated calomel electrode. The amount of absorbed hydrogen increases with decreasing applied potential. Under the same applied potential, the amount of hydrogen absorbed in the 2.0{\%} NaF solution is larger than that in the 0.2{\%} NaF solution. Hydrogen thermal desorption is observed in the temperature range from 250-300 to 700 °C. For the 2.0{\%} NaF solution, compared with the 0.2{\%} NaF solution, the amount of hydrogen desorbed in the high temperature range is large. The hydrogen desorption behavior for neutral NaF solutions under the applied potential is not necessarily consistent with that for acidulated phosphate fluoride solutions without the applied potential reported previously.",
    keywords = "Corrosion, Fluoride, Hydrogen embrittlement, Thermal desorption analysis, Titanium",
    author = "Katsutoshi Takashima and Ken'ichi Yokoyama and Kenzo Asaoka and Jun'ichi Sakai",
    year = "2007",
    month = "4",
    day = "4",
    doi = "10.1016/j.jallcom.2006.05.036",
    language = "English",
    volume = "431",
    pages = "203--207",
    journal = "Journal of Alloys and Compounds",
    issn = "0925-8388",
    publisher = "Elsevier BV",
    number = "1-2",

    }

    TY - JOUR

    T1 - Effects of potential on hydrogen absorption and desorption behaviors of titanium in neutral fluoride solutions

    AU - Takashima, Katsutoshi

    AU - Yokoyama, Ken'ichi

    AU - Asaoka, Kenzo

    AU - Sakai, Jun'ichi

    PY - 2007/4/4

    Y1 - 2007/4/4

    N2 - The effects of potential on the hydrogen absorption and desorption of commercial pure titanium immersed in neutral 2.0% and 0.2% NaF solutions for 24 h have been investigated by hydrogen thermal desorption analysis. Hydrogen absorption occurs in both solutions under less noble potentials than -1.2 V versus a saturated calomel electrode. The amount of absorbed hydrogen increases with decreasing applied potential. Under the same applied potential, the amount of hydrogen absorbed in the 2.0% NaF solution is larger than that in the 0.2% NaF solution. Hydrogen thermal desorption is observed in the temperature range from 250-300 to 700 °C. For the 2.0% NaF solution, compared with the 0.2% NaF solution, the amount of hydrogen desorbed in the high temperature range is large. The hydrogen desorption behavior for neutral NaF solutions under the applied potential is not necessarily consistent with that for acidulated phosphate fluoride solutions without the applied potential reported previously.

    AB - The effects of potential on the hydrogen absorption and desorption of commercial pure titanium immersed in neutral 2.0% and 0.2% NaF solutions for 24 h have been investigated by hydrogen thermal desorption analysis. Hydrogen absorption occurs in both solutions under less noble potentials than -1.2 V versus a saturated calomel electrode. The amount of absorbed hydrogen increases with decreasing applied potential. Under the same applied potential, the amount of hydrogen absorbed in the 2.0% NaF solution is larger than that in the 0.2% NaF solution. Hydrogen thermal desorption is observed in the temperature range from 250-300 to 700 °C. For the 2.0% NaF solution, compared with the 0.2% NaF solution, the amount of hydrogen desorbed in the high temperature range is large. The hydrogen desorption behavior for neutral NaF solutions under the applied potential is not necessarily consistent with that for acidulated phosphate fluoride solutions without the applied potential reported previously.

    KW - Corrosion

    KW - Fluoride

    KW - Hydrogen embrittlement

    KW - Thermal desorption analysis

    KW - Titanium

    UR - http://www.scopus.com/inward/record.url?scp=33847301505&partnerID=8YFLogxK

    UR - http://www.scopus.com/inward/citedby.url?scp=33847301505&partnerID=8YFLogxK

    U2 - 10.1016/j.jallcom.2006.05.036

    DO - 10.1016/j.jallcom.2006.05.036

    M3 - Article

    VL - 431

    SP - 203

    EP - 207

    JO - Journal of Alloys and Compounds

    JF - Journal of Alloys and Compounds

    SN - 0925-8388

    IS - 1-2

    ER -