Efficient charge transport of a radical polyether/SWCNT composite electrode for an organic radical battery with high charge-storage density

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    26 Citations (Scopus)

    Abstract

    A crosslinked poly(4-glycidyloxy TEMPO) was synthesized via anionic ring-opening copolymerization of 4-glycidyloxy TEMPO and a diglycidyl ether using a pentaerythritol/phosphazene base initiator. A fast and reversible charge storage capability was established for the polyether/SWCNT composite layer with a large layer thickness of several tens of micrometres, despite the low SWCNT content of 10% which was much closer to the percolation limit than the amount required for the previously reported TEMPO-substituted polymethacrylate. This journal is

    Original languageEnglish
    Pages (from-to)15448-15452
    Number of pages5
    JournalRSC Advances
    Volume5
    Issue number20
    DOIs
    Publication statusPublished - 2015

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    Polyethers
    Copolymerization
    Charge transfer
    Ethers
    Electrodes
    Composite materials
    Ether
    TEMPO

    ASJC Scopus subject areas

    • Chemical Engineering(all)
    • Chemistry(all)

    Cite this

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    abstract = "A crosslinked poly(4-glycidyloxy TEMPO) was synthesized via anionic ring-opening copolymerization of 4-glycidyloxy TEMPO and a diglycidyl ether using a pentaerythritol/phosphazene base initiator. A fast and reversible charge storage capability was established for the polyether/SWCNT composite layer with a large layer thickness of several tens of micrometres, despite the low SWCNT content of 10{\%} which was much closer to the percolation limit than the amount required for the previously reported TEMPO-substituted polymethacrylate. This journal is",
    author = "Takashi Sukegawa and Kan Hatakeyama and Kenichi Oyaizu and Hiroyuki Nishide",
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    T1 - Efficient charge transport of a radical polyether/SWCNT composite electrode for an organic radical battery with high charge-storage density

    AU - Sukegawa, Takashi

    AU - Hatakeyama, Kan

    AU - Oyaizu, Kenichi

    AU - Nishide, Hiroyuki

    PY - 2015

    Y1 - 2015

    N2 - A crosslinked poly(4-glycidyloxy TEMPO) was synthesized via anionic ring-opening copolymerization of 4-glycidyloxy TEMPO and a diglycidyl ether using a pentaerythritol/phosphazene base initiator. A fast and reversible charge storage capability was established for the polyether/SWCNT composite layer with a large layer thickness of several tens of micrometres, despite the low SWCNT content of 10% which was much closer to the percolation limit than the amount required for the previously reported TEMPO-substituted polymethacrylate. This journal is

    AB - A crosslinked poly(4-glycidyloxy TEMPO) was synthesized via anionic ring-opening copolymerization of 4-glycidyloxy TEMPO and a diglycidyl ether using a pentaerythritol/phosphazene base initiator. A fast and reversible charge storage capability was established for the polyether/SWCNT composite layer with a large layer thickness of several tens of micrometres, despite the low SWCNT content of 10% which was much closer to the percolation limit than the amount required for the previously reported TEMPO-substituted polymethacrylate. This journal is

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