Electro-optic properties of Pb(Zr1-xTix)O 3 (X = 0, 0.3, 0.6) films prepared by aerosol deposition

Masafumi Nakada, Keishi Ohashi, Jun Akedo

Research output: Contribution to journalArticle

22 Citations (Scopus)

Abstract

We measured annealing temperature and the Zr-to-Ti concentration ratio dependence of the electro-optic (EO) effect for highly transparent Pb(Zr 1-xTix)O3 [PZT] films more than 1 μm thick, directly deposited on glass substrates by aerosol deposition (AD). X-ray diffraction patterns show that as-deposited AD films have a large strain and lattice distortions, and these affects can be attenuated by increasing annealing temperature. The dielectric constant of AD-PZT films increased with annealing temperature, which is consistent with the X-ray diffraction measurement. The EO effect was enhanced with increasing Zr concentration, and a linear EO coefficient (rc) of 102 pm/V was obtained for the PbZr 0.6T0.4O3 film annealed at 600°C, whose composition is near its morphotropic phase boundary. The rc of PbZr0.6T0.4O3 films increased with annealing temperature, and the film annealed at 850°C showed an rc of 168 pm/V. The EO measurements show that AD is a highly promising film-deposition method for optical devices such as EO modulators and optical switches.

Original languageEnglish
Pages (from-to)L1088-L1090
JournalJapanese Journal of Applied Physics, Part 2: Letters
Volume44
Issue number33-36
DOIs
Publication statusPublished - 2005 Aug 26
Externally publishedYes

Keywords

  • Aerosol deposition
  • Complex oxide
  • Electro-optic properties
  • Film
  • PZT

ASJC Scopus subject areas

  • Engineering(all)
  • Physics and Astronomy (miscellaneous)
  • Physics and Astronomy(all)

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