TY - JOUR
T1 - Electro-oxidative Polymerization of 2, 6-DimethyIphenoxide Ion in the Presence of Bromide Ion as a Mediator
AU - Yamamoto, Kimihisa
AU - Nishide, Hiroyuki
AU - Tsuchida, Eishun
PY - 1986
Y1 - 1986
N2 - Anodic oxidation of 2, 6-dimethylphenol in an alkaline dichloromethane in the presence of bromide ion gave poly[oxy(2, 6-dimethyl-1, 4-phenylene] with high efficiency. 4-Bromo-2, 6-dimethylphenol was isolated from the reaction mixture during the electrolysis. Bromide ion is assumed to serve as a mediator of electro-oxidative polymerization. The mechanism of this polymerization was discussed on the basis of results obtained in the measurements including cyclic voltammetry and double potential-step chronocoulometry.
AB - Anodic oxidation of 2, 6-dimethylphenol in an alkaline dichloromethane in the presence of bromide ion gave poly[oxy(2, 6-dimethyl-1, 4-phenylene] with high efficiency. 4-Bromo-2, 6-dimethylphenol was isolated from the reaction mixture during the electrolysis. Bromide ion is assumed to serve as a mediator of electro-oxidative polymerization. The mechanism of this polymerization was discussed on the basis of results obtained in the measurements including cyclic voltammetry and double potential-step chronocoulometry.
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U2 - 10.1246/nikkashi.1986.152
DO - 10.1246/nikkashi.1986.152
M3 - Article
AN - SCOPUS:85016540446
SN - 0369-4577
VL - 1986
SP - 152
EP - 156
JO - Nippon Kagaku Kaishi / Chemical Society of Japan - Chemistry and Industrial Chemistry Journal
JF - Nippon Kagaku Kaishi / Chemical Society of Japan - Chemistry and Industrial Chemistry Journal
IS - 2
ER -