Electro-oxidative Polymerization of 2, 6-DimethyIphenoxide Ion in the Presence of Bromide Ion as a Mediator

Kimihisa Yamamoto, Hiroyuki Nishide, Eishun Tsuchida

Research output: Contribution to journalArticle

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Abstract

Anodic oxidation of 2, 6-dimethylphenol in an alkaline dichloromethane in the presence of bromide ion gave poly[oxy(2, 6-dimethyl-1, 4-phenylene] with high efficiency. 4-Bromo-2, 6-dimethylphenol was isolated from the reaction mixture during the electrolysis. Bromide ion is assumed to serve as a mediator of electro-oxidative polymerization. The mechanism of this polymerization was discussed on the basis of results obtained in the measurements including cyclic voltammetry and double potential-step chronocoulometry.

Original languageEnglish
Pages (from-to)152-156
Number of pages5
JournalNippon Kagaku Kaishi
Volume1986
Issue number2
DOIs
Publication statusPublished - 1986

Fingerprint

Bromides
Polymerization
Ions
Methylene Chloride
Dichloromethane
Anodic oxidation
Electrolysis
Cyclic voltammetry
arylox
2,6-xylenol
4-bromo-2,6-dimethylphenol

ASJC Scopus subject areas

  • Chemistry(all)

Cite this

Electro-oxidative Polymerization of 2, 6-DimethyIphenoxide Ion in the Presence of Bromide Ion as a Mediator. / Yamamoto, Kimihisa; Nishide, Hiroyuki; Tsuchida, Eishun.

In: Nippon Kagaku Kaishi, Vol. 1986, No. 2, 1986, p. 152-156.

Research output: Contribution to journalArticle

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