Electrocatalytic properties of metal adatoms in a potential range negative to Nernstian bulk deposition

Xuekun Xing; Daniel Alberto Scherson

doi:10.1016/0022-0728(89)85042-9

Electrocatalytic properties of metal adatoms in a potential range negative to Nernstian bulk deposition

Xuekun Xing, Daniel Alberto Scherson

Research output: Contribution to journal › Article › peer-review

23 Citations (Scopus)

Abstract

The formation of submonolayers of Cu adatoms on polycrystalline Au in 0.1 M HClO₄ solutions containing only perchlorate anions has been found to proceed at unusually slow rates. This has made it possible to examine the electrocatalytic activity of submonolayer coverages of Cu adatoms exhibiting UPD like properties at potentials more negative than Cu bulk deposition. Rotating ring disk measurements have provided evidence that such layers show electrocatalytic properties for the reduction of nitrate. This process proceeds by a parallel mechanism yielding nitrite as one of the intermediates.

Original language	English
Pages (from-to)	273-284
Number of pages	12
Journal	Journal of Electroanalytical Chemistry
Volume	270
Issue number	1-2
DOIs	https://doi.org/10.1016/0022-0728(89)85042-9
Publication status	Published - 1989 Oct 10
Externally published	Yes

ASJC Scopus subject areas

Analytical Chemistry
Chemical Engineering(all)
Electrochemistry

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title = "Electrocatalytic properties of metal adatoms in a potential range negative to Nernstian bulk deposition",

abstract = "The formation of submonolayers of Cu adatoms on polycrystalline Au in 0.1 M HClO4 solutions containing only perchlorate anions has been found to proceed at unusually slow rates. This has made it possible to examine the electrocatalytic activity of submonolayer coverages of Cu adatoms exhibiting UPD like properties at potentials more negative than Cu bulk deposition. Rotating ring disk measurements have provided evidence that such layers show electrocatalytic properties for the reduction of nitrate. This process proceeds by a parallel mechanism yielding nitrite as one of the intermediates.",

author = "Xuekun Xing and Scherson, {Daniel Alberto}",

year = "1989",

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AU - Xing, Xuekun

AU - Scherson, Daniel Alberto

PY - 1989/10/10

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N2 - The formation of submonolayers of Cu adatoms on polycrystalline Au in 0.1 M HClO4 solutions containing only perchlorate anions has been found to proceed at unusually slow rates. This has made it possible to examine the electrocatalytic activity of submonolayer coverages of Cu adatoms exhibiting UPD like properties at potentials more negative than Cu bulk deposition. Rotating ring disk measurements have provided evidence that such layers show electrocatalytic properties for the reduction of nitrate. This process proceeds by a parallel mechanism yielding nitrite as one of the intermediates.

AB - The formation of submonolayers of Cu adatoms on polycrystalline Au in 0.1 M HClO4 solutions containing only perchlorate anions has been found to proceed at unusually slow rates. This has made it possible to examine the electrocatalytic activity of submonolayer coverages of Cu adatoms exhibiting UPD like properties at potentials more negative than Cu bulk deposition. Rotating ring disk measurements have provided evidence that such layers show electrocatalytic properties for the reduction of nitrate. This process proceeds by a parallel mechanism yielding nitrite as one of the intermediates.

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