Electrochemical and in situ Raman studies of embedded carbon particle electrodes in nonaqueous liquid electrolytes

Dana A. Totir; Daniel Alberto Scherson

doi:10.1149/1.1391119

Electrochemical and in situ Raman studies of embedded carbon particle electrodes in nonaqueous liquid electrolytes

Dana A. Totir, Daniel Alberto Scherson

Research output: Contribution to journal › Article › peer-review

28 Citations (Scopus)

Abstract

A method is described for the electrochemical and in situ Raman spectroscopy characterization of particles of graphite and other carbonaceous materials used as lithium intercalation battery anodes. This method relies on high-pressure embedding of such particles on thermally annealed Ni foils and therefore does not require binders or other additives that may interfere with the electrochemical and spectroscopic behavior. The results obtained with embedded KS-44 graphite and MCF28 carbon microfibers in 1 M LiClO₄ in 1:1 (by volume) ethylene carbonate/diethyl carbonate mixtures yielded cyclic voltammetric and in situ Raman features that were in very good agreement with those reported by others for similar materials using more conventional electrode formulations.

Original language	English
Pages (from-to)	263-265
Number of pages	3
Journal	Electrochemical and Solid-State Letters
Volume	3
Issue number	6
DOIs	https://doi.org/10.1149/1.1391119
Publication status	Published - 2000 Jun 1
Externally published	Yes

ASJC Scopus subject areas

Electrochemistry
Materials Science(all)

Access to Document

10.1149/1.1391119

Cite this

@article{9c121f93157749948ce8c86e4008839a,

title = "Electrochemical and in situ Raman studies of embedded carbon particle electrodes in nonaqueous liquid electrolytes",

abstract = "A method is described for the electrochemical and in situ Raman spectroscopy characterization of particles of graphite and other carbonaceous materials used as lithium intercalation battery anodes. This method relies on high-pressure embedding of such particles on thermally annealed Ni foils and therefore does not require binders or other additives that may interfere with the electrochemical and spectroscopic behavior. The results obtained with embedded KS-44 graphite and MCF28 carbon microfibers in 1 M LiClO4 in 1:1 (by volume) ethylene carbonate/diethyl carbonate mixtures yielded cyclic voltammetric and in situ Raman features that were in very good agreement with those reported by others for similar materials using more conventional electrode formulations.",

author = "Totir, {Dana A.} and Scherson, {Daniel Alberto}",

year = "2000",

month = jun,

day = "1",

doi = "10.1149/1.1391119",

language = "English",

volume = "3",

pages = "263--265",

journal = "Electrochemical and Solid-State Letters",

issn = "1099-0062",

publisher = "Electrochemical Society, Inc.",

number = "6",

}

TY - JOUR

T1 - Electrochemical and in situ Raman studies of embedded carbon particle electrodes in nonaqueous liquid electrolytes

AU - Totir, Dana A.

AU - Scherson, Daniel Alberto

PY - 2000/6/1

Y1 - 2000/6/1

N2 - A method is described for the electrochemical and in situ Raman spectroscopy characterization of particles of graphite and other carbonaceous materials used as lithium intercalation battery anodes. This method relies on high-pressure embedding of such particles on thermally annealed Ni foils and therefore does not require binders or other additives that may interfere with the electrochemical and spectroscopic behavior. The results obtained with embedded KS-44 graphite and MCF28 carbon microfibers in 1 M LiClO4 in 1:1 (by volume) ethylene carbonate/diethyl carbonate mixtures yielded cyclic voltammetric and in situ Raman features that were in very good agreement with those reported by others for similar materials using more conventional electrode formulations.

AB - A method is described for the electrochemical and in situ Raman spectroscopy characterization of particles of graphite and other carbonaceous materials used as lithium intercalation battery anodes. This method relies on high-pressure embedding of such particles on thermally annealed Ni foils and therefore does not require binders or other additives that may interfere with the electrochemical and spectroscopic behavior. The results obtained with embedded KS-44 graphite and MCF28 carbon microfibers in 1 M LiClO4 in 1:1 (by volume) ethylene carbonate/diethyl carbonate mixtures yielded cyclic voltammetric and in situ Raman features that were in very good agreement with those reported by others for similar materials using more conventional electrode formulations.

UR - http://www.scopus.com/inward/record.url?scp=0033700777&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=0033700777&partnerID=8YFLogxK

U2 - 10.1149/1.1391119

DO - 10.1149/1.1391119

M3 - Article

AN - SCOPUS:0033700777

SN - 1099-0062

VL - 3

SP - 263

EP - 265

JO - Electrochemical and Solid-State Letters

JF - Electrochemical and Solid-State Letters

IS - 6

ER -

Electrochemical and in situ Raman studies of embedded carbon particle electrodes in nonaqueous liquid electrolytes

Abstract

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this