Electrochemical characterization of lithiated transition metal oxide cathode particles in the absence of carbon, binders and other additives

Dana A. Totir, Boris D. Cahan, Daniel Alberto Scherson

Research output: Contribution to journalArticle

42 Citations (Scopus)

Abstract

A novel method is herein described for the electrochemical characterization of lithiated transition metal oxides in powder form as cathode materials for lithium ion batteries. The procedure involves application of sufficiently high pressures to a layer of oxide powder evently dispersed on the surface of a Au foil so as to embed the particles into the soft metal substrate, thereby avoiding the use of carbon, binders and other additives. Implementation of this methodology for battery-grade LiMn2O4, LiCoO2 and LiCo0.15Ni0.85O2 particles supplied by various commercial sources yielded electrodes of excellent mechanical integrity displaying close to ideal cyclic voltammetric behavior in electrolytes of relevance to battery applications. The charge capacity of each of these compounds could be estimated quantitatively by dissolving the array of oxide particles in acid, once the electrochemical experiments were completed and then determining the amount of metal in the solutions by ICP-MS analysis. An analysis of voltammetric measurements as a function of scan rate yielded values of mean diffusion coefficients for Li in LiMn2O4 on the order of 5 × 10-10 cm2 s-1.

Original languageEnglish
Pages (from-to)161-166
Number of pages6
JournalElectrochimica Acta
Volume45
Issue number1
DOIs
Publication statusPublished - 1999 Sep 30
Externally publishedYes

ASJC Scopus subject areas

  • Chemical Engineering(all)
  • Electrochemistry

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