Electrochemical impedance spectroscopy analysis for lithium-ion battery using Li4Ti5O12 anode

Tao Hang; Daikichi Mukoyama; Hiroki Nara; Norio Takami; Toshiyuki Momma; Tetsuya Osaka

doi:10.1016/j.jpowsour.2012.09.010

Electrochemical impedance spectroscopy analysis for lithium-ion battery using Li₄Ti₅O₁₂ anode

Tao Hang, Daikichi Mukoyama, Hiroki Nara, Norio Takami, Toshiyuki Momma^*, Tetsuya Osaka

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

84 Citations (Scopus)

Abstract

The impedance of Li-ion battery using a Li₄Ti₅O₁₂ (LTO) anode for high-power applications was measured at various depths of discharge and temperatures during chargeedischarge cycles. The measured impedance was interpreted with an equivalent circuit made up of anode and cathode, in which the cathode component was composed of two particle size factors. The values obtained for equivalent circuit elements by modeling were in good agreement with the results measured by other techniques, and indicated that the capacity fade of this Li-ion battery due to cycling is mainly caused by the increase of interfacial resistance and a decrease in the capacity of the LiCoO₂ cathode. These results suggest that the cyclability of this LIB was improved by using an LTO anode, and show the validity of the equivalent circuit for interpreting the causes of capacity fade.

Original language	English
Pages (from-to)	442-447
Number of pages	6
Journal	Journal of Power Sources
Volume	222
DOIs	https://doi.org/10.1016/j.jpowsour.2012.09.010
Publication status	Published - 2013 Jan 15

Keywords

Capacity fade
Electrochemical impedance spectroscopy
Li-ion battery

ASJC Scopus subject areas

Renewable Energy, Sustainability and the Environment
Energy Engineering and Power Technology
Physical and Theoretical Chemistry
Electrical and Electronic Engineering

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

Access to Document

10.1016/j.jpowsour.2012.09.010

Cite this

@article{107f63c453c54f9d917b6b2793cd34fd,

title = "Electrochemical impedance spectroscopy analysis for lithium-ion battery using Li4Ti5O12 anode",

abstract = "The impedance of Li-ion battery using a Li4Ti5O12 (LTO) anode for high-power applications was measured at various depths of discharge and temperatures during chargeedischarge cycles. The measured impedance was interpreted with an equivalent circuit made up of anode and cathode, in which the cathode component was composed of two particle size factors. The values obtained for equivalent circuit elements by modeling were in good agreement with the results measured by other techniques, and indicated that the capacity fade of this Li-ion battery due to cycling is mainly caused by the increase of interfacial resistance and a decrease in the capacity of the LiCoO2 cathode. These results suggest that the cyclability of this LIB was improved by using an LTO anode, and show the validity of the equivalent circuit for interpreting the causes of capacity fade.",

keywords = "Capacity fade, Electrochemical impedance spectroscopy, Li-ion battery",

author = "Tao Hang and Daikichi Mukoyama and Hiroki Nara and Norio Takami and Toshiyuki Momma and Tetsuya Osaka",

note = "Funding Information: This work was supported by “Research & Development Initiative for Scientific Innovation of New Generation Batteries” from the New Energy and Industrial technology Development Organization of Japan and a Grant-in-Aid for Specially Promoted Research “Establishment of Electrochemical Device Engineering” from the Ministry of Education, Culture, Sports, Science and Technology, Japan and done in the Center for Practical Chemical Wisdom of Global COE.",

year = "2013",

month = jan,

day = "15",

doi = "10.1016/j.jpowsour.2012.09.010",

language = "English",

volume = "222",

pages = "442--447",

journal = "Journal of Power Sources",

issn = "0378-7753",

publisher = "Elsevier",

}

TY - JOUR

T1 - Electrochemical impedance spectroscopy analysis for lithium-ion battery using Li4Ti5O12 anode

AU - Hang, Tao

AU - Mukoyama, Daikichi

AU - Nara, Hiroki

AU - Takami, Norio

AU - Momma, Toshiyuki

AU - Osaka, Tetsuya

N1 - Funding Information: This work was supported by “Research & Development Initiative for Scientific Innovation of New Generation Batteries” from the New Energy and Industrial technology Development Organization of Japan and a Grant-in-Aid for Specially Promoted Research “Establishment of Electrochemical Device Engineering” from the Ministry of Education, Culture, Sports, Science and Technology, Japan and done in the Center for Practical Chemical Wisdom of Global COE.

PY - 2013/1/15

Y1 - 2013/1/15

N2 - The impedance of Li-ion battery using a Li4Ti5O12 (LTO) anode for high-power applications was measured at various depths of discharge and temperatures during chargeedischarge cycles. The measured impedance was interpreted with an equivalent circuit made up of anode and cathode, in which the cathode component was composed of two particle size factors. The values obtained for equivalent circuit elements by modeling were in good agreement with the results measured by other techniques, and indicated that the capacity fade of this Li-ion battery due to cycling is mainly caused by the increase of interfacial resistance and a decrease in the capacity of the LiCoO2 cathode. These results suggest that the cyclability of this LIB was improved by using an LTO anode, and show the validity of the equivalent circuit for interpreting the causes of capacity fade.

AB - The impedance of Li-ion battery using a Li4Ti5O12 (LTO) anode for high-power applications was measured at various depths of discharge and temperatures during chargeedischarge cycles. The measured impedance was interpreted with an equivalent circuit made up of anode and cathode, in which the cathode component was composed of two particle size factors. The values obtained for equivalent circuit elements by modeling were in good agreement with the results measured by other techniques, and indicated that the capacity fade of this Li-ion battery due to cycling is mainly caused by the increase of interfacial resistance and a decrease in the capacity of the LiCoO2 cathode. These results suggest that the cyclability of this LIB was improved by using an LTO anode, and show the validity of the equivalent circuit for interpreting the causes of capacity fade.

KW - Capacity fade

KW - Electrochemical impedance spectroscopy

KW - Li-ion battery

UR - http://www.scopus.com/inward/record.url?scp=84866544118&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=84866544118&partnerID=8YFLogxK

U2 - 10.1016/j.jpowsour.2012.09.010

DO - 10.1016/j.jpowsour.2012.09.010

M3 - Article

AN - SCOPUS:84866544118

SN - 0378-7753

VL - 222

SP - 442

EP - 447

JO - Journal of Power Sources

JF - Journal of Power Sources

ER -