Electrochemical oxidation of Ni(111)c(4×2)-CO in alkaline electrolytes

Kuilong Wang; Gary S. Chottiner; Daniel Alberto Scherson

Electrochemical oxidation of Ni(111)c(4×2)-CO in alkaline electrolytes

Kuilong Wang, Gary S. Chottiner, Daniel Alberto Scherson

Research output: Contribution to journal › Article › peer-review

Abstract

The electrochemical properties of Ni(111)c(4×2)-CO surfaces prepared in ultrahigh vacuum (UHV) have been examined in 0.1 M KOH using a UHV electrochemistry transfer system. The results obtained indicate that the CO layer remains intact up to the moment of contact with the electrolyte and can be subsequently electrooxidized quantitatively to yield CO₂ (e.g., mostly carbonate) as the product.

Original language	English
Pages (from-to)	6742-6744
Number of pages	3
Journal	Journal of physical chemistry
Volume	96
Issue number	16
Publication status	Published - 1992 Dec 1
Externally published	Yes

ASJC Scopus subject areas

Physical and Theoretical Chemistry

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title = "Electrochemical oxidation of Ni(111)c(4×2)-CO in alkaline electrolytes",

abstract = "The electrochemical properties of Ni(111)c(4×2)-CO surfaces prepared in ultrahigh vacuum (UHV) have been examined in 0.1 M KOH using a UHV electrochemistry transfer system. The results obtained indicate that the CO layer remains intact up to the moment of contact with the electrolyte and can be subsequently electrooxidized quantitatively to yield CO2 (e.g., mostly carbonate) as the product.",

author = "Kuilong Wang and Chottiner, {Gary S.} and Scherson, {Daniel Alberto}",

year = "1992",

month = dec,

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language = "English",

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AU - Wang, Kuilong

AU - Chottiner, Gary S.

AU - Scherson, Daniel Alberto

PY - 1992/12/1

Y1 - 1992/12/1

N2 - The electrochemical properties of Ni(111)c(4×2)-CO surfaces prepared in ultrahigh vacuum (UHV) have been examined in 0.1 M KOH using a UHV electrochemistry transfer system. The results obtained indicate that the CO layer remains intact up to the moment of contact with the electrolyte and can be subsequently electrooxidized quantitatively to yield CO2 (e.g., mostly carbonate) as the product.

AB - The electrochemical properties of Ni(111)c(4×2)-CO surfaces prepared in ultrahigh vacuum (UHV) have been examined in 0.1 M KOH using a UHV electrochemistry transfer system. The results obtained indicate that the CO layer remains intact up to the moment of contact with the electrolyte and can be subsequently electrooxidized quantitatively to yield CO2 (e.g., mostly carbonate) as the product.

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