Abstract
In order to clarify the origin of the graded magnetic properties by the substrate rotational speed for electroless CoNiP films, electrochemical characteristics such as mixed potential and polarization behaviors were investigated. The results of mixed potential analysis revealed that the cathodic and anodic partial reactions in this system were diffusion- and reaction-controlled state, respectively. It was shown that the mixed potential of the CoNiP deposition with the substrate rotational speed was dominated mainly by the deposition reaction of Co. The results of the polarization curves for each metal ion clarified that the Co deposition is in the diffusion-controlled state, whereas such a tendency did not appear for the deposition of Ni. This suggests that such a difference in deposition behaviors between Co and Ni with respect to the rotational speed of the substrate results in the formation of graded film properties.
| Original language | English |
|---|---|
| Pages (from-to) | 4138-4141 |
| Number of pages | 4 |
| Journal | Journal of the Electrochemical Society |
| Volume | 147 |
| Issue number | 11 |
| DOIs | |
| Publication status | Published - 2000 Nov |
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ASJC Scopus subject areas
- Electrochemistry
- Surfaces, Coatings and Films
- Surfaces and Interfaces
Cite this
Electrochemical studies on the deposition process of electroless CoNiP films with graded magnetic properties. / Homma, Takayuki; Kita, Yosuke; Osaka, Tetsuya.
In: Journal of the Electrochemical Society, Vol. 147, No. 11, 11.2000, p. 4138-4141.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Electrochemical studies on the deposition process of electroless CoNiP films with graded magnetic properties
AU - Homma, Takayuki
AU - Kita, Yosuke
AU - Osaka, Tetsuya
PY - 2000/11
Y1 - 2000/11
N2 - In order to clarify the origin of the graded magnetic properties by the substrate rotational speed for electroless CoNiP films, electrochemical characteristics such as mixed potential and polarization behaviors were investigated. The results of mixed potential analysis revealed that the cathodic and anodic partial reactions in this system were diffusion- and reaction-controlled state, respectively. It was shown that the mixed potential of the CoNiP deposition with the substrate rotational speed was dominated mainly by the deposition reaction of Co. The results of the polarization curves for each metal ion clarified that the Co deposition is in the diffusion-controlled state, whereas such a tendency did not appear for the deposition of Ni. This suggests that such a difference in deposition behaviors between Co and Ni with respect to the rotational speed of the substrate results in the formation of graded film properties.
AB - In order to clarify the origin of the graded magnetic properties by the substrate rotational speed for electroless CoNiP films, electrochemical characteristics such as mixed potential and polarization behaviors were investigated. The results of mixed potential analysis revealed that the cathodic and anodic partial reactions in this system were diffusion- and reaction-controlled state, respectively. It was shown that the mixed potential of the CoNiP deposition with the substrate rotational speed was dominated mainly by the deposition reaction of Co. The results of the polarization curves for each metal ion clarified that the Co deposition is in the diffusion-controlled state, whereas such a tendency did not appear for the deposition of Ni. This suggests that such a difference in deposition behaviors between Co and Ni with respect to the rotational speed of the substrate results in the formation of graded film properties.
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UR - http://www.scopus.com/inward/citedby.url?scp=0034321222&partnerID=8YFLogxK
U2 - 10.1149/1.1394031
DO - 10.1149/1.1394031
M3 - Article
VL - 147
SP - 4138
EP - 4141
JO - Journal of the Electrochemical Society
JF - Journal of the Electrochemical Society
SN - 0013-4651
IS - 11
ER -