Electrochemical study of the nitroxyl radical derivatives built in the π-conjugated poly(phenylenevinylene) skeleton

Shuichi Toriu, Takashi Kaneko, Hiroyuki Nishide, Eishun Tsuchida

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The electrochemical oxidation and reduction of the stable neutral nitroxyl radical gave the oxoaminium salt and hydroxylamine or nitroxyl anion, respectively. The electrochemical behavior of the N-butylnitroxyl radicals or N-butylhydroxylamines built in to various phenylenevinylene species were discussed in connection with its developed π-conjugated structure based on cyclic voltammetric measurements. The aromatic nitroxyl radical showed two pairs of oxidation-reduction waves, but the acidic proton (hydroxylamine) changed its cathodic peak to a broad one with a shift to the anodic side. The π-conjugated poly(phenylenevinylene) backbone and mobile proton of the hydroxylamine unstabilized the nitroxyl radical by retaining the energy gap.

Original languageEnglish
Pages (from-to)707-710
Number of pages4
JournalPolymers for Advanced Technologies
Issue number11
Publication statusPublished - 1995 Nov


ASJC Scopus subject areas

  • Polymers and Plastics

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