Electrodeposited Sn-Ni alloy film as a high capacity anode material for lithium-ion secondary batteries

Hitomi Mukaibo, Tomohide Sumi, Tokihiko Yokoshima, Toshiyuki Momma, Tetsuya Osaka

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148 Citations (Scopus)

Abstract

Thin Sn-Ni alloy films containing various Sn/Ni ratios were prepared by electrodeposition and characterized as lithium-ion secondary battery anodes. The initial drop in discharge capacity varied with the Sn content of the sample; i.e., for samples with 54 atom % Sn and 62 atom % Sn, the drop was less than 100 mAh/g, whereas for those with 84 atom % Sn and 92 atom % Sn, the drop exceeded 500 mAh/g. Among these thin films, the 62 atom % Sn film showed the highest reversible capacity of ca. 650 mAh/g at about the 70th cycle, whereas the other samples (54 atom % Sn, 84 atom % Sn, 92 atom % Sn) showed a capacity of 300 mAh/g.

Original languageEnglish
JournalElectrochemical and Solid-State Letters
Volume6
Issue number10
DOIs
Publication statusPublished - 2003 Oct

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storage batteries
Secondary batteries
Lithium
Anodes
anodes
lithium
Ions
Atoms
atoms
ions
Electrodeposition
electrodeposition
Thin films
cycles
thin films

ASJC Scopus subject areas

  • Electrochemistry
  • Materials Science(all)

Cite this

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abstract = "Thin Sn-Ni alloy films containing various Sn/Ni ratios were prepared by electrodeposition and characterized as lithium-ion secondary battery anodes. The initial drop in discharge capacity varied with the Sn content of the sample; i.e., for samples with 54 atom {\%} Sn and 62 atom {\%} Sn, the drop was less than 100 mAh/g, whereas for those with 84 atom {\%} Sn and 92 atom {\%} Sn, the drop exceeded 500 mAh/g. Among these thin films, the 62 atom {\%} Sn film showed the highest reversible capacity of ca. 650 mAh/g at about the 70th cycle, whereas the other samples (54 atom {\%} Sn, 84 atom {\%} Sn, 92 atom {\%} Sn) showed a capacity of 300 mAh/g.",
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T1 - Electrodeposited Sn-Ni alloy film as a high capacity anode material for lithium-ion secondary batteries

AU - Mukaibo, Hitomi

AU - Sumi, Tomohide

AU - Yokoshima, Tokihiko

AU - Momma, Toshiyuki

AU - Osaka, Tetsuya

PY - 2003/10

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N2 - Thin Sn-Ni alloy films containing various Sn/Ni ratios were prepared by electrodeposition and characterized as lithium-ion secondary battery anodes. The initial drop in discharge capacity varied with the Sn content of the sample; i.e., for samples with 54 atom % Sn and 62 atom % Sn, the drop was less than 100 mAh/g, whereas for those with 84 atom % Sn and 92 atom % Sn, the drop exceeded 500 mAh/g. Among these thin films, the 62 atom % Sn film showed the highest reversible capacity of ca. 650 mAh/g at about the 70th cycle, whereas the other samples (54 atom % Sn, 84 atom % Sn, 92 atom % Sn) showed a capacity of 300 mAh/g.

AB - Thin Sn-Ni alloy films containing various Sn/Ni ratios were prepared by electrodeposition and characterized as lithium-ion secondary battery anodes. The initial drop in discharge capacity varied with the Sn content of the sample; i.e., for samples with 54 atom % Sn and 62 atom % Sn, the drop was less than 100 mAh/g, whereas for those with 84 atom % Sn and 92 atom % Sn, the drop exceeded 500 mAh/g. Among these thin films, the 62 atom % Sn film showed the highest reversible capacity of ca. 650 mAh/g at about the 70th cycle, whereas the other samples (54 atom % Sn, 84 atom % Sn, 92 atom % Sn) showed a capacity of 300 mAh/g.

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