Electroluminescent Behaviors of Electrochemically Cross-Linkable Poly(benzyl ether) Terthiophene Dendrimers

Jin Young Park, Rigoberto C. Advincula

Research output: Contribution to journalArticle

Abstract

In this study, the electroluminescent (EL) properties of electrochemically cross-linkable, terthiophene terminated poly(benzyl ether) dendrimers (G0-3T and G1-3T DNs) are investigated. In noncross-linked 3T DNs, there is either no emission or a low-intensity emission due to poor charge transfer of the isolated terthiophene (3T) oligomers at the periphery of the DNs. However, increase in the length of conjugation via electrochemical cross-linking leads to the emission of a yellowish color. It is seen that the emission of this color is dependent on the dendritic structures and effectively controlled charge trapping. Thus, these results suggest that the dendritic molecular structure, which is associated with the conjugated length of the emissive peripheral units and the generation of the dendrimers, is an important factor in controlling EL properties. (Figure presented.).

Original languageEnglish
Pages (from-to)1948-1954
Number of pages7
JournalMacromolecular Chemistry and Physics
Volume217
Issue number17
DOIs
Publication statusPublished - 2016 Sep 1
Externally publishedYes

Fingerprint

Dendrimers
dendrimers
Ether
Ethers
ethers
Color
Charge trapping
Oligomers
Molecular structure
Charge transfer
color
conjugation
oligomers
molecular structure
trapping
charge transfer
alpha-terthienyl

Keywords

  • conjugation
  • dendrimer
  • electrochemical cross-linking
  • electroluminescence
  • light-emitting diodes

ASJC Scopus subject areas

  • Condensed Matter Physics
  • Physical and Theoretical Chemistry
  • Polymers and Plastics
  • Organic Chemistry
  • Materials Chemistry

Cite this

Electroluminescent Behaviors of Electrochemically Cross-Linkable Poly(benzyl ether) Terthiophene Dendrimers. / Park, Jin Young; Advincula, Rigoberto C.

In: Macromolecular Chemistry and Physics, Vol. 217, No. 17, 01.09.2016, p. 1948-1954.

Research output: Contribution to journalArticle

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