ELECTRON-TRANSFER BEHAVIOR OF THE METAL COMPLEXES ATTACHED TO POLYMER MATRICES.

Eishun Tsuchida, Hiroyuki Nishide

Research output: Chapter in Book/Report/Conference proceedingConference contribution

1 Citation (Scopus)

Abstract

Interfacial electron-transfer reactions between polymer-bonded metal complexes and the substrates in solution phase were studied to show colloid aspects of polymer catalysis. A polymer-bonded metal complex often shows a specifically catalytic behavior, because the electron-transfer reactivity is strongly affected by the polymer matrix that surrounds the complex. A polymer-Cu complex coated electrode was successfully applied as the interfacial catalyst for the oxidative polymerization of phenol.

Original languageEnglish
Title of host publicationACS Symposium Series
EditorsE.J. Vandenberg, A. Blumstein, M.J. Bowden, Jett C. Arthur, Joginder Lal, R.M. Ottenbrite
Place of PublicationWashington, DC, USA
PublisherACS
Pages49-63
Number of pages15
ISBN (Print)0841207658
Publication statusPublished - 1983

ASJC Scopus subject areas

  • Chemistry(all)

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  • Cite this

    Tsuchida, E., & Nishide, H. (1983). ELECTRON-TRANSFER BEHAVIOR OF THE METAL COMPLEXES ATTACHED TO POLYMER MATRICES. In E. J. Vandenberg, A. Blumstein, M. J. Bowden, J. C. Arthur, J. Lal, & R. M. Ottenbrite (Eds.), ACS Symposium Series (pp. 49-63). ACS.