Electro‐oxidative polymerization of 1,3‐Cyclohexadiene

Kimihisa Yamamoto, Toshio Asada, Hiroyuki Nishide, Eishun Tsuchida

Research output: Contribution to journalArticle

2 Citations (Scopus)

Abstract

1,3‐Cyclohexadiene is electropolymerized at a lower applied potential, compared with the polymerization of other alkene compounds, to give insoluble polymer film on an electrode. The formed polymer contains a phenylene repeated unit, which is confirmed by IR, 1H‐ and 13C‐NMR spectroscopy. Poly(cyclohexene) produced by the electropolymerization is partially aromatized by the oxidation to form a phenylene unit which is accompanied by an elimination of a proton.

Original languageEnglish
Pages (from-to)207-210
Number of pages4
JournalPolymers for Advanced Technologies
Volume1
Issue number3-4
DOIs
Publication statusPublished - 1990

Fingerprint

Electropolymerization
Alkenes
Polymer films
Olefins
Protons
Polymers
Polymerization
Spectroscopy
Oxidation
Electrodes
cyclohexene

Keywords

  • Cationic oxidation
  • Cyclohexadiene
  • Electro‐polymerization
  • Poly(cyclohexene)
  • Poly(phenylene)

ASJC Scopus subject areas

  • Polymers and Plastics

Cite this

Electro‐oxidative polymerization of 1,3‐Cyclohexadiene. / Yamamoto, Kimihisa; Asada, Toshio; Nishide, Hiroyuki; Tsuchida, Eishun.

In: Polymers for Advanced Technologies, Vol. 1, No. 3-4, 1990, p. 207-210.

Research output: Contribution to journalArticle

Yamamoto, Kimihisa ; Asada, Toshio ; Nishide, Hiroyuki ; Tsuchida, Eishun. / Electro‐oxidative polymerization of 1,3‐Cyclohexadiene. In: Polymers for Advanced Technologies. 1990 ; Vol. 1, No. 3-4. pp. 207-210.
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