Electropolymerizable terthiophene-terminated poly(aryl ether) dendrimers with naphthalene and perylene cores

Ramakrishna Ponnapati, Mary Jane Felipe, Rigoberto Advincula

Research output: Contribution to journalArticle

16 Citations (Scopus)

Abstract

We describe the synthesis and characterization of a new series of poly(aryl ether) dendrimers with both donor and acceptor moieties. By incorporating p-type terthiophene and n-type perylene and naphthalene diimides into one molecule, we have achieved a dual electrochromic material. These dendrimers were designed to act as electrochemically active precursor polymers, which bear the electroactive terthiophene group that can be cross-linked electrochemically to form conjugated polymer network (CPN) films. Characterization of the optical and redox properties shows that it is possible to incorporate donor and acceptor moieties in the same molecule with retention of doping properties. The films made by electrochemical polymerization are highly active in both the p- and n-doping processes and have been investigated by spectroelectrochemical methods.

Original languageEnglish
Pages (from-to)7530-7537
Number of pages8
JournalMacromolecules
Volume44
Issue number19
DOIs
Publication statusPublished - 2011 Oct 11
Externally publishedYes

Fingerprint

Perylene
Dendrimers
Naphthalene
Ether
Ethers
Doping (additives)
Molecules
Electropolymerization
Conjugated polymers
Polymers
alpha-terthienyl
naphthalene

ASJC Scopus subject areas

  • Organic Chemistry
  • Materials Chemistry
  • Polymers and Plastics
  • Inorganic Chemistry

Cite this

Electropolymerizable terthiophene-terminated poly(aryl ether) dendrimers with naphthalene and perylene cores. / Ponnapati, Ramakrishna; Felipe, Mary Jane; Advincula, Rigoberto.

In: Macromolecules, Vol. 44, No. 19, 11.10.2011, p. 7530-7537.

Research output: Contribution to journalArticle

Ponnapati, Ramakrishna ; Felipe, Mary Jane ; Advincula, Rigoberto. / Electropolymerizable terthiophene-terminated poly(aryl ether) dendrimers with naphthalene and perylene cores. In: Macromolecules. 2011 ; Vol. 44, No. 19. pp. 7530-7537.
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