Electropolymerization of thiophene having porphyrin group and its application to superoxide sensor

Manabu Hoshino, Hidenori Murata, Kenichi Oyaizu, Makoto Yuasa

Research output: Chapter in Book/Report/Conference proceedingConference contribution

Abstract

Iron 5-(3-thienyl)-10,15,20-triethylporphyrin was electropolymerized in supercritical carbon dioxide (scCO2) to yield the corresponding conductive polymer film. The film was analyzed by scanning electron microscopy, laser microscopy and AFM. It was revealed that the thiophene-porphyrin film synthesized in scCO2 was more dense and smoother than those synthesized in dichloromethane. The electrocatalyst was applied to a superoxide anion radical sensor, and its detection sensitivity was drastically increased.

Original languageEnglish
Title of host publicationPolymer Preprints, Japan
Pages2972
Number of pages1
Volume55
Edition2
Publication statusPublished - 2006
Externally publishedYes
Event55th Society of Polymer Science Japan Symposium on Macromolecules - Toyama, Japan
Duration: 2006 Sep 202006 Sep 22

Other

Other55th Society of Polymer Science Japan Symposium on Macromolecules
CountryJapan
CityToyama
Period06/9/2006/9/22

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Keywords

  • Electrocatalyst
  • Electropolymerization
  • Porphyrin complex
  • Supercritical carbon dioxide
  • Superoxide

ASJC Scopus subject areas

  • Engineering(all)

Cite this

Hoshino, M., Murata, H., Oyaizu, K., & Yuasa, M. (2006). Electropolymerization of thiophene having porphyrin group and its application to superoxide sensor. In Polymer Preprints, Japan (2 ed., Vol. 55, pp. 2972)