Enantioselective incorporation of dicarboxylate guests by octacalcium phosphate

Taishi Yokoi, Shingo MacHida, Yoshiyuki Sugahara, Masami Hashimoto, Satoshi Kitaoka

    Research output: Contribution to journalArticle

    2 Citations (Scopus)

    Abstract

    Enantioselectivity by octacalcium phosphate (OCP) is revealed through the incorporation of (S)-(-)-methylsuccinic acid (MeSuc) into its crystal lattice, with hardly any (R)-(+)-MeSuc incorporated. This phenomenon clearly indicates that OCP recognizes the steric structures of guest molecules, extending chiral recognition in inorganic materials to three-dimensional crystal growth.

    Original languageEnglish
    Pages (from-to)6524-6527
    Number of pages4
    JournalChemical Communications
    Volume53
    Issue number48
    DOIs
    Publication statusPublished - 2017

    Fingerprint

    Phosphates
    Acids
    Enantioselectivity
    Crystallization
    Crystal growth
    Crystal lattices
    Molecules
    methylsuccinic acid
    octacalcium phosphate

    ASJC Scopus subject areas

    • Catalysis
    • Electronic, Optical and Magnetic Materials
    • Ceramics and Composites
    • Chemistry(all)
    • Surfaces, Coatings and Films
    • Metals and Alloys
    • Materials Chemistry

    Cite this

    Enantioselective incorporation of dicarboxylate guests by octacalcium phosphate. / Yokoi, Taishi; MacHida, Shingo; Sugahara, Yoshiyuki; Hashimoto, Masami; Kitaoka, Satoshi.

    In: Chemical Communications, Vol. 53, No. 48, 2017, p. 6524-6527.

    Research output: Contribution to journalArticle

    Yokoi, Taishi ; MacHida, Shingo ; Sugahara, Yoshiyuki ; Hashimoto, Masami ; Kitaoka, Satoshi. / Enantioselective incorporation of dicarboxylate guests by octacalcium phosphate. In: Chemical Communications. 2017 ; Vol. 53, No. 48. pp. 6524-6527.
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