Enantioselective intramolecular [2+2+2] cycloaddition of dienynes for the construction of adjacent three chiral centers

Takanori Shibata, Mayumi Otomo, Kohei Endo

    Research output: Contribution to journalArticle

    11 Citations (Scopus)

    Abstract

    A chiral rhodium catalyst realized the first intramolecular [2+2+2] cycloaddition of yne-ene-enes, and chiral multicyclic cyclohexenes with adjacent three chiral centers were afforded with high to excellent ee.

    Original languageEnglish
    Article numberU00910ST
    Pages (from-to)1235-1238
    Number of pages4
    JournalSynlett
    Issue number8
    DOIs
    Publication statusPublished - 2010

    Fingerprint

    Cyclohexenes
    Rhodium
    Cycloaddition
    Catalysts

    Keywords

    • Catalysis
    • Chirality
    • Cycloaddition
    • Multicyclic
    • Rhodium

    ASJC Scopus subject areas

    • Organic Chemistry

    Cite this

    Enantioselective intramolecular [2+2+2] cycloaddition of dienynes for the construction of adjacent three chiral centers. / Shibata, Takanori; Otomo, Mayumi; Endo, Kohei.

    In: Synlett, No. 8, U00910ST, 2010, p. 1235-1238.

    Research output: Contribution to journalArticle

    @article{ec7b8abb55e5438fb1d8ea7cc2c2b8da,
    title = "Enantioselective intramolecular [2+2+2] cycloaddition of dienynes for the construction of adjacent three chiral centers",
    abstract = "A chiral rhodium catalyst realized the first intramolecular [2+2+2] cycloaddition of yne-ene-enes, and chiral multicyclic cyclohexenes with adjacent three chiral centers were afforded with high to excellent ee.",
    keywords = "Catalysis, Chirality, Cycloaddition, Multicyclic, Rhodium",
    author = "Takanori Shibata and Mayumi Otomo and Kohei Endo",
    year = "2010",
    doi = "10.1055/s-0029-1219815",
    language = "English",
    pages = "1235--1238",
    journal = "Synlett",
    issn = "0936-5214",
    publisher = "Georg Thieme Verlag",
    number = "8",

    }

    TY - JOUR

    T1 - Enantioselective intramolecular [2+2+2] cycloaddition of dienynes for the construction of adjacent three chiral centers

    AU - Shibata, Takanori

    AU - Otomo, Mayumi

    AU - Endo, Kohei

    PY - 2010

    Y1 - 2010

    N2 - A chiral rhodium catalyst realized the first intramolecular [2+2+2] cycloaddition of yne-ene-enes, and chiral multicyclic cyclohexenes with adjacent three chiral centers were afforded with high to excellent ee.

    AB - A chiral rhodium catalyst realized the first intramolecular [2+2+2] cycloaddition of yne-ene-enes, and chiral multicyclic cyclohexenes with adjacent three chiral centers were afforded with high to excellent ee.

    KW - Catalysis

    KW - Chirality

    KW - Cycloaddition

    KW - Multicyclic

    KW - Rhodium

    UR - http://www.scopus.com/inward/record.url?scp=77952082333&partnerID=8YFLogxK

    UR - http://www.scopus.com/inward/citedby.url?scp=77952082333&partnerID=8YFLogxK

    U2 - 10.1055/s-0029-1219815

    DO - 10.1055/s-0029-1219815

    M3 - Article

    AN - SCOPUS:77952082333

    SP - 1235

    EP - 1238

    JO - Synlett

    JF - Synlett

    SN - 0936-5214

    IS - 8

    M1 - U00910ST

    ER -