Enantioselective intramolecular [2+2+2] cycloaddition of dienynes for the construction of adjacent three chiral centers

Takanori Shibata, Mayumi Otomo, Kohei Endo

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    Abstract

    A chiral rhodium catalyst realized the first intramolecular [2+2+2] cycloaddition of yne-ene-enes, and chiral multicyclic cyclohexenes with adjacent three chiral centers were afforded with high to excellent ee.

    Original languageEnglish
    Article numberU00910ST
    Pages (from-to)1235-1238
    Number of pages4
    JournalSynlett
    Issue number8
    DOIs
    Publication statusPublished - 2010

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    Keywords

    • Catalysis
    • Chirality
    • Cycloaddition
    • Multicyclic
    • Rhodium

    ASJC Scopus subject areas

    • Organic Chemistry

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