Enantioselective intramolecular [2+2+2] cycloaddition of dienynes for the construction of adjacent three chiral centers

Takanori Shibata, Mayumi Otomo, Kohei Endo

Research output: Contribution to journalArticle

12 Citations (Scopus)

Abstract

A chiral rhodium catalyst realized the first intramolecular [2+2+2] cycloaddition of yne-ene-enes, and chiral multicyclic cyclohexenes with adjacent three chiral centers were afforded with high to excellent ee.

Original languageEnglish
Article numberU00910ST
Pages (from-to)1235-1238
Number of pages4
JournalSynlett
Issue number8
DOIs
Publication statusPublished - 2010 May 14

Keywords

  • Catalysis
  • Chirality
  • Cycloaddition
  • Multicyclic
  • Rhodium

ASJC Scopus subject areas

  • Organic Chemistry

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