Enantioselective nucleophilic substitution of a 6,6-bicyclic dienyl acetate by palladium-chiral phosphine catalyst

Isao Shimizu, Yoshiyuki Matsumoto, Masahiro Nishikawa, Tamotsu Kawahara, Akiharu Satake, Akio Yamamoto

Research output: Contribution to journalArticlepeer-review

12 Citations (Scopus)

Abstract

The enantioselective nucleophilic substitution of (±)-2β-acetoxy-4aβ-methyl-2,3,4,4a,5,6-hexahydronaphthalene with dimethyl malonate anion was performed in the presence of palladium-chiral ligand catalysts to give optically active 2-di(methoxycarbonyl)methyl-4a-methyl-2,3,4,4a,5,6-hexahydronaphthalenes.

Original languageEnglish
Pages (from-to)983-984
Number of pages2
JournalChemistry Letters
Issue number10
Publication statusPublished - 1998

ASJC Scopus subject areas

  • Chemistry(all)

Fingerprint Dive into the research topics of 'Enantioselective nucleophilic substitution of a 6,6-bicyclic dienyl acetate by palladium-chiral phosphine catalyst'. Together they form a unique fingerprint.

Cite this