Abstract
The first synthesis of planar-chiral benzosiloloferrocenes was achieved by the intramolecular reaction of 2-(dimethylhydrosilyl)arylferrocenes. The enantioselective cross dehydrogenative coupling of an sp<sup>2</sup> C-H bond of ferrocene with a Si-H bond proceeded efficiently with the use of a Rh-chiral diene catalyst.
| Original language | English |
|---|---|
| Pages (from-to) | 7802-7804 |
| Number of pages | 3 |
| Journal | Chemical Communications |
| Volume | 51 |
| Issue number | 37 |
| DOIs | |
| Publication status | Published - 2015 May 7 |
ASJC Scopus subject areas
- Chemistry(all)
- Catalysis
- Ceramics and Composites
- Electronic, Optical and Magnetic Materials
- Surfaces, Coatings and Films
- Materials Chemistry
- Metals and Alloys
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Cite this
Shibata, T., Shizuno, T., & Sasaki, T. (2015). Enantioselective synthesis of planar-chiral benzosiloloferrocenes by Rh-catalyzed intramolecular C-H silylation. Chemical Communications, 51(37), 7802-7804. https://doi.org/10.1039/c5cc00723b