Enantioselective synthesis of planar-chiral benzosiloloferrocenes by Rh-catalyzed intramolecular C-H silylation

Takanori Shibata; Tsubasa Shizuno; Tomoya Sasaki

doi:10.1039/c5cc00723b

Enantioselective synthesis of planar-chiral benzosiloloferrocenes by Rh-catalyzed intramolecular C-H silylation

Takanori Shibata, Tsubasa Shizuno, Tomoya Sasaki

Research output: Contribution to journal › Article

54 Citations (Scopus)

Abstract

The first synthesis of planar-chiral benzosiloloferrocenes was achieved by the intramolecular reaction of 2-(dimethylhydrosilyl)arylferrocenes. The enantioselective cross dehydrogenative coupling of an sp<sup>2</sup> C-H bond of ferrocene with a Si-H bond proceeded efficiently with the use of a Rh-chiral diene catalyst.

Original language	English
Pages (from-to)	7802-7804
Number of pages	3
Journal	Chemical Communications
Volume	51
Issue number	37
DOIs	https://doi.org/10.1039/c5cc00723b
Publication status	Published - 2015 May 7

Fingerprint

ASJC Scopus subject areas

Chemistry(all)
Catalysis
Ceramics and Composites
Electronic, Optical and Magnetic Materials
Surfaces, Coatings and Films
Materials Chemistry
Metals and Alloys

Cite this

Shibata, T., Shizuno, T., & Sasaki, T. (2015). Enantioselective synthesis of planar-chiral benzosiloloferrocenes by Rh-catalyzed intramolecular C-H silylation. Chemical Communications, 51(37), 7802-7804. https://doi.org/10.1039/c5cc00723b

@article{42440f4a26194bccb7a99134f7739812,

title = "Enantioselective synthesis of planar-chiral benzosiloloferrocenes by Rh-catalyzed intramolecular C-H silylation",

abstract = "The first synthesis of planar-chiral benzosiloloferrocenes was achieved by the intramolecular reaction of 2-(dimethylhydrosilyl)arylferrocenes. The enantioselective cross dehydrogenative coupling of an sp2 C-H bond of ferrocene with a Si-H bond proceeded efficiently with the use of a Rh-chiral diene catalyst.",

author = "Takanori Shibata and Tsubasa Shizuno and Tomoya Sasaki",

year = "2015",

month = may

day = "7",

doi = "10.1039/c5cc00723b",

language = "English",

volume = "51",

pages = "7802--7804",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

number = "37",

}

TY - JOUR

T1 - Enantioselective synthesis of planar-chiral benzosiloloferrocenes by Rh-catalyzed intramolecular C-H silylation

AU - Shibata, Takanori

AU - Shizuno, Tsubasa

AU - Sasaki, Tomoya

PY - 2015/5/7

Y1 - 2015/5/7

N2 - The first synthesis of planar-chiral benzosiloloferrocenes was achieved by the intramolecular reaction of 2-(dimethylhydrosilyl)arylferrocenes. The enantioselective cross dehydrogenative coupling of an sp2 C-H bond of ferrocene with a Si-H bond proceeded efficiently with the use of a Rh-chiral diene catalyst.

AB - The first synthesis of planar-chiral benzosiloloferrocenes was achieved by the intramolecular reaction of 2-(dimethylhydrosilyl)arylferrocenes. The enantioselective cross dehydrogenative coupling of an sp2 C-H bond of ferrocene with a Si-H bond proceeded efficiently with the use of a Rh-chiral diene catalyst.

UR - http://www.scopus.com/inward/record.url?scp=84928801929&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=84928801929&partnerID=8YFLogxK

U2 - 10.1039/c5cc00723b

DO - 10.1039/c5cc00723b

M3 - Article

AN - SCOPUS:84928801929

VL - 51

SP - 7802

EP - 7804

JO - Chemical Communications

JF - Chemical Communications

SN - 1359-7345

IS - 37

ER -

Access to Document

10.1039/c5cc00723b