Enantioselective synthesis of planar-chiral benzosiloloferrocenes by Rh-catalyzed intramolecular C-H silylation

Takanori Shibata; Tsubasa Shizuno; Tomoya Sasaki

doi:10.1039/c5cc00723b

Enantioselective synthesis of planar-chiral benzosiloloferrocenes by Rh-catalyzed intramolecular C-H silylation

Takanori Shibata, Tsubasa Shizuno, Tomoya Sasaki

School of Advanced Science and Engineering

Research output: Contribution to journal › Article › peer-review

66 Citations (Scopus)

Abstract

The first synthesis of planar-chiral benzosiloloferrocenes was achieved by the intramolecular reaction of 2-(dimethylhydrosilyl)arylferrocenes. The enantioselective cross dehydrogenative coupling of an sp² C-H bond of ferrocene with a Si-H bond proceeded efficiently with the use of a Rh-chiral diene catalyst.

Original language	English
Pages (from-to)	7802-7804
Number of pages	3
Journal	Chemical Communications
Volume	51
Issue number	37
DOIs	https://doi.org/10.1039/c5cc00723b
Publication status	Published - 2015 May 7

ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
Chemistry(all)
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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abstract = "The first synthesis of planar-chiral benzosiloloferrocenes was achieved by the intramolecular reaction of 2-(dimethylhydrosilyl)arylferrocenes. The enantioselective cross dehydrogenative coupling of an sp2 C-H bond of ferrocene with a Si-H bond proceeded efficiently with the use of a Rh-chiral diene catalyst.",

author = "Takanori Shibata and Tsubasa Shizuno and Tomoya Sasaki",

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AU - Shibata, Takanori

AU - Shizuno, Tsubasa

AU - Sasaki, Tomoya

N1 - Publisher Copyright: © The Royal Society of Chemistry 2015.

PY - 2015/5/7

Y1 - 2015/5/7

N2 - The first synthesis of planar-chiral benzosiloloferrocenes was achieved by the intramolecular reaction of 2-(dimethylhydrosilyl)arylferrocenes. The enantioselective cross dehydrogenative coupling of an sp2 C-H bond of ferrocene with a Si-H bond proceeded efficiently with the use of a Rh-chiral diene catalyst.

AB - The first synthesis of planar-chiral benzosiloloferrocenes was achieved by the intramolecular reaction of 2-(dimethylhydrosilyl)arylferrocenes. The enantioselective cross dehydrogenative coupling of an sp2 C-H bond of ferrocene with a Si-H bond proceeded efficiently with the use of a Rh-chiral diene catalyst.

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U2 - 10.1039/c5cc00723b

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Enantioselective synthesis of planar-chiral benzosiloloferrocenes by Rh-catalyzed intramolecular C-H silylation

Abstract

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