Abstract
The first synthesis of planar-chiral benzosiloloferrocenes was achieved by the intramolecular reaction of 2-(dimethylhydrosilyl)arylferrocenes. The enantioselective cross dehydrogenative coupling of an sp<sup>2</sup> C-H bond of ferrocene with a Si-H bond proceeded efficiently with the use of a Rh-chiral diene catalyst.
Original language | English |
---|---|
Pages (from-to) | 7802-7804 |
Number of pages | 3 |
Journal | Chemical Communications |
Volume | 51 |
Issue number | 37 |
DOIs | |
Publication status | Published - 2015 May 7 |
ASJC Scopus subject areas
- Chemistry(all)
- Catalysis
- Ceramics and Composites
- Electronic, Optical and Magnetic Materials
- Surfaces, Coatings and Films
- Materials Chemistry
- Metals and Alloys