Enantioselective synthesis of planar-chiral benzosiloloferrocenes by Rh-catalyzed intramolecular C-H silylation

Takanori Shibata, Tsubasa Shizuno, Tomoya Sasaki

    Research output: Contribution to journal › Article

    50 Citations (Scopus)

    Abstract

    The first synthesis of planar-chiral benzosiloloferrocenes was achieved by the intramolecular reaction of 2-(dimethylhydrosilyl)arylferrocenes. The enantioselective cross dehydrogenative coupling of an sp<sup>2</sup> C-H bond of ferrocene with a Si-H bond proceeded efficiently with the use of a Rh-chiral diene catalyst.

    Original languageEnglish
    Pages (from-to)7802-7804
    Number of pages3
    JournalChemical Communications
    Volume51
    Issue number37
    DOIs
    Publication statusPublished - 2015 May 7

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    Catalysts
    ferrocene

    ASJC Scopus subject areas

    • Chemistry(all)
    • Catalysis
    • Ceramics and Composites
    • Electronic, Optical and Magnetic Materials
    • Surfaces, Coatings and Films
    • Materials Chemistry
    • Metals and Alloys

    Cite this

    Enantioselective synthesis of planar-chiral benzosiloloferrocenes by Rh-catalyzed intramolecular C-H silylation. / Shibata, Takanori; Shizuno, Tsubasa; Sasaki, Tomoya.

    In: Chemical Communications, Vol. 51, No. 37, 07.05.2015, p. 7802-7804.

    Research output: Contribution to journal › Article

    Shibata, T, Shizuno, T & Sasaki, T 2015, 'Enantioselective synthesis of planar-chiral benzosiloloferrocenes by Rh-catalyzed intramolecular C-H silylation', Chemical Communications, vol. 51, no. 37, pp. 7802-7804. https://doi.org/10.1039/c5cc00723b
    Shibata T, Shizuno T, Sasaki T. Enantioselective synthesis of planar-chiral benzosiloloferrocenes by Rh-catalyzed intramolecular C-H silylation. Chemical Communications. 2015 May 7;51(37):7802-7804. https://doi.org/10.1039/c5cc00723b
    Shibata, Takanori ; Shizuno, Tsubasa ; Sasaki, Tomoya. / Enantioselective synthesis of planar-chiral benzosiloloferrocenes by Rh-catalyzed intramolecular C-H silylation. In: Chemical Communications. 2015 ; Vol. 51, No. 37. pp. 7802-7804.
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