Enhanced Wettability Changes by Synergistic Effect of Micro/Nanoimprinted Substrates and Grafted Thermoresponsive Polymer Brushes

Kenichi Nagase, Takahiro Onuma, Masayuki Yamato, Naoya Takeda, Teruo Okano

    Research output: Contribution to journalArticle

    9 Citations (Scopus)

    Abstract

    Thermoresponsive polymer brushes are grafted on micro/nanostructured polymer substrates as new intelligent interfaces that synergistically enhance wettability changes in response to external temperature stimuli. Thermoplastic poly(styrene-co-4-vinylbenzyl chloride) [P(St-co-VBC)] is synthesized using radical polymerization and spin-coated on a glass substrate. Micro/nanopillar and hole patterns are imprinted on the P(St-co-VBC) layer using thermal nanoimprint lithography. Poly(N-isopropylacrylamide) (PIPAAm) brushes are grafted on the micro/nanostructured P(St-co-VBC) layer through surface-initiated atom-transfer radical polymerization using 4-vinylbenzyl chloride as the initiator. The imprinted micro/nanostructures and grafted PIPAAm brush chain lengths affect the surface wettability. Combinations of nanopillars or nanoholes (diameter 500 nm) and longer PIPAAm brushes enhance hydrophobic/hydrophilic changes in response to temperature changes, compared with the flat substrate. The thermoresponsive hydrophobic/hydrophilic transition is synergistically enhanced by the nanostructured surface changing from Cassie-Baxter to Wenzel states. This PIPAAm-brush-modified micro/nanostructured P(St-co-VBC) is a new intelligent interface that effectively changes wettability in response to external temperature changes. Novel thermoresponsive interfaces showing significant wettability changes are fabricated by nanoimprinting a poly(styrene-co-4-vinylbenzyl chloride) layer and subsequent surface-initiated atom transfer radical polymerization of poly(N-isopropylacrylamide) (IPAAm). Combinations of nanopillars or nanoholes and longer PIPAAm brushes enhance hydrophobic/hydrophilic changes in response to temperature changes, compared with a flat substrate.

    Original languageEnglish
    Pages (from-to)1965-1970
    Number of pages6
    JournalMacromolecular Rapid Communications
    Volume36
    Issue number22
    DOIs
    Publication statusPublished - 2015 Nov 1

    Fingerprint

    Brushes
    Styrene
    Wetting
    Chlorides
    Polymers
    Substrates
    Atom transfer radical polymerization
    Nanoimprint lithography
    Temperature
    Free radical polymerization
    Chain length
    Thermoplastics
    poly-N-isopropylacrylamide
    Nanostructures
    Glass

    Keywords

    • contact angles
    • intelligent interfaces
    • nanoimprint lithography
    • polymer brushes
    • thermoresponsive

    ASJC Scopus subject areas

    • Organic Chemistry
    • Materials Chemistry
    • Polymers and Plastics

    Cite this

    Enhanced Wettability Changes by Synergistic Effect of Micro/Nanoimprinted Substrates and Grafted Thermoresponsive Polymer Brushes. / Nagase, Kenichi; Onuma, Takahiro; Yamato, Masayuki; Takeda, Naoya; Okano, Teruo.

    In: Macromolecular Rapid Communications, Vol. 36, No. 22, 01.11.2015, p. 1965-1970.

    Research output: Contribution to journalArticle

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