Esterification of the Silanol Groups in the Mesoporous Silica Derived from Kanemite

Tatsuo Kimura, Kazuo Kuroda, Yoshiyuki Sugahara, Kazuyuki Kuroda

    Research output: Contribution to journal › Article

    60 Citations (Scopus)

    Abstract

    Silanol groups in the mesoporous silica derived from a layered silicate, kanemite (NaHSi2O5 · 3H2O), were esterified with alcohols (CnH2n+1OH; n = 2, 4, and 8). Most of the silanol groups in the mesopores were modified with ethanol though some silanol groups remained after the reactions with 1-dutanol and 1-octanol. With the increase in the alkyl chain lengths of the alcohols, the pore sizes of the esterified products decreased and the hydrophobicity increased.

    Original languageEnglish
    Pages (from-to)127-132
    Number of pages6
    JournalJournal of Porous Materials
    Volume5
    Issue number2
    Publication statusPublished - 1998

    Fingerprint

    Esterification
    Silicon Dioxide
    Alcohols
    Silica
    silicon dioxide
    alcohols
    Hydrophobicity
    Chain length
    1-Octanol
    Pore size
    Silicates
    Ethanol
    hydrophobicity
    silicates
    ethyl alcohol
    porosity
    products
    silanol

    Keywords

    • Esterification
    • Hydrophobicity
    • Mesoporous silica
    • Pore size
    • Silanol group

    ASJC Scopus subject areas

    • Catalysis
    • Chemistry (miscellaneous)
    • Physical and Theoretical Chemistry
    • Materials Science(all)

    Cite this

    Esterification of the Silanol Groups in the Mesoporous Silica Derived from Kanemite. / Kimura, Tatsuo; Kuroda, Kazuo; Sugahara, Yoshiyuki; Kuroda, Kazuyuki.

    In: Journal of Porous Materials, Vol. 5, No. 2, 1998, p. 127-132.

    Research output: Contribution to journal › Article

    Kimura, T, Kuroda, K, Sugahara, Y & Kuroda, K 1998, 'Esterification of the Silanol Groups in the Mesoporous Silica Derived from Kanemite', Journal of Porous Materials, vol. 5, no. 2, pp. 127-132.
    Kimura T, Kuroda K, Sugahara Y, Kuroda K. Esterification of the Silanol Groups in the Mesoporous Silica Derived from Kanemite. Journal of Porous Materials. 1998;5(2):127-132.
    Kimura, Tatsuo ; Kuroda, Kazuo ; Sugahara, Yoshiyuki ; Kuroda, Kazuyuki. / Esterification of the Silanol Groups in the Mesoporous Silica Derived from Kanemite. In: Journal of Porous Materials. 1998 ; Vol. 5, No. 2. pp. 127-132.
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