Evaluating surface protonic transport on cerium oxide via electrochemical impedance spectroscopy measurement

Ryo Manabe, Sindre Østby Stub, Truls Norby, Yasushi Sekine

    Research output: Contribution to journalArticle

    10 Citations (Scopus)

    Abstract

    Surface protonic transport on cerium oxide (CeO2) was investigated using electrochemical impedance spectroscopy (EIS). CeO2 pellets showing low relative density: approximately 60%, was prepared for the purpose. The structure and morphology of the prepared CeO2 pellets were confirmed from XRD and SEM measurements. Results show that the pellets had a pure cubic phase, with open pores on which water can be adsorbed. Electrochemical impedance spectroscopy measurements were taken to evaluate the surface protonic transport on CeO2 as a function of temperature and as a function of partial pressure of water (PH2O) at 400 °C. Investigations of the temperature dependence of the conductivity revealed that only the conductivities of surface grain bulk (σintra) and surface grain boundary (σinter) increased with decreasing temperatures under wet conditions (PH2O = 0.026 atm). The PH2O dependence of surface conductivities (σintra and σinter) revealed that σintra increases strongly with PH2O at 400 °C. These findings provide evidence that water adsorbates play an important role in surface protonic transport on CeO2 at low temperatures. Surface protonic transport at low temperatures can contribute to the expansion of applications for electrical and catalytic processes.

    Original languageEnglish
    Pages (from-to)45-49
    Number of pages5
    JournalSolid State Communications
    Volume270
    DOIs
    Publication statusPublished - 2018 Feb 1

    Keywords

    • A. Cerium oxide
    • B. Low relative density
    • D. Surface protonics
    • E. AC impedance measurement

    ASJC Scopus subject areas

    • Chemistry(all)
    • Condensed Matter Physics
    • Materials Chemistry

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