Evidence for the formation of interlayer polyacrylonitrile in kaolinite

Y. Sugahara, S. Satokawa, K. Kuroda, C. Kato

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Abstract

A kaolinite-polymer intercalation complex was apparently formed for the first time by the polymerization of acrylonitrile between the kaolinite layers. A kaolinite-ammonium acetate intercalation complex was dispersed in acrylonitrile monomer. The monomer was apparently incorporated between the layers by displacing intercalated ammonium acetate. After the removal of excess monomer, the intercalation complex was heated to cause polymerization. The resulting kaolinite-polyacrylonitrile (PAN) intercalate showed a basal spacing of ~13-14 A. On heating the complex at 220°C for 1 hr in air, the spacing decreased slightly. The hydrogen bond between the hydroxyls of kaolinite and probably the C≡N group of PAN was not affected after heating at 220°C. Even after heating at 400°C, the layers expanded. Because the starting kaolinite-ammonium acetate intercalation complex decomposed at a much lower temperature, these observations strongly suggest the presence of PAN between the layers. -Authors

Original languageEnglish
Pages (from-to)343-348
Number of pages6
JournalClays & Clay Minerals
Volume36
Issue number4
DOIs
Publication statusPublished - 1988 Jan 1

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ASJC Scopus subject areas

  • Water Science and Technology
  • Soil Science
  • Geochemistry and Petrology
  • Earth and Planetary Sciences (miscellaneous)

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