Evidence for the HCl+(A) formation in the reaction of Ne(3P) with the size-selected HCl dimer using an electrostatic hexapole field

Kohei Imura; Hiroshi Ohoyama; Toshio Kasai

doi:10.1246/cl.2001.1136

Evidence for the HCl⁺(A) formation in the reaction of Ne(³P) with the size-selected HCl dimer using an electrostatic hexapole field

Kohei Imura, Hiroshi Ohoyama, Toshio Kasai

School of Advanced Science and Engineering

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Abstract

Penning ionization of Ne(³P) metastable atom with size-selected HCl dimer was studied by using an electrostatic hexapole field and chemiluminescence detection. We found that the HCl dimer can also produce HCl⁺(A) ions in the reaction with Ne(³P) just like its corresponding monomer reaction. The internal energy distribution of HCl⁺(A) in the dimer reaction is cooler than that in the monomer reaction, reflecting the third-body effect due to the other HCl in the dimer.

Original language	English
Pages (from-to)	1136-1137
Number of pages	2
Journal	Chemistry Letters
Issue number	11
DOIs	https://doi.org/10.1246/cl.2001.1136
Publication status	Published - 2001 Jan 1

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Imura, K., Ohoyama, H., & Kasai, T. (2001). Evidence for the HCl⁺(A) formation in the reaction of Ne(³P) with the size-selected HCl dimer using an electrostatic hexapole field. Chemistry Letters, (11), 1136-1137. https://doi.org/10.1246/cl.2001.1136

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10.1246/cl.2001.1136