Abstract
HCl dimers were prepared in a pulsed supersonic beam of neat HCl. The dimers were focused in an electrostatic hexapole field. Using computer simulation, the focusing curve could be fit, assuming contributions from both first and second order Stark effects. The dipole moment, based on simulation, was found to be 1.5 ± 0.1 D. The ability to observe an effective dipole moment in a system where the donor-acceptor tunneling is fast is surprising. It may indicate that the understanding of the interaction of floppy systems with hexapole field is not complete.
| Original language | English |
|---|---|
| Pages (from-to) | 356-360 |
| Number of pages | 5 |
| Journal | Chemical Physics Letters |
| Volume | 259 |
| Issue number | 3-4 |
| Publication status | Published - 1996 Sep 6 |
| Externally published | Yes |
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ASJC Scopus subject areas
- Physical and Theoretical Chemistry
- Spectroscopy
- Atomic and Molecular Physics, and Optics
Cite this
Experimental determination of the dipole moment of HCl dimer using an electrostatic hexapole field. / Imura, Kohei; Kasai, T.; Ohoyama, H.; Takahashi, H.; Naaman, R.
In: Chemical Physics Letters, Vol. 259, No. 3-4, 06.09.1996, p. 356-360.Research output: Contribution to journal › Article
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TY - JOUR
T1 - Experimental determination of the dipole moment of HCl dimer using an electrostatic hexapole field
AU - Imura, Kohei
AU - Kasai, T.
AU - Ohoyama, H.
AU - Takahashi, H.
AU - Naaman, R.
PY - 1996/9/6
Y1 - 1996/9/6
N2 - HCl dimers were prepared in a pulsed supersonic beam of neat HCl. The dimers were focused in an electrostatic hexapole field. Using computer simulation, the focusing curve could be fit, assuming contributions from both first and second order Stark effects. The dipole moment, based on simulation, was found to be 1.5 ± 0.1 D. The ability to observe an effective dipole moment in a system where the donor-acceptor tunneling is fast is surprising. It may indicate that the understanding of the interaction of floppy systems with hexapole field is not complete.
AB - HCl dimers were prepared in a pulsed supersonic beam of neat HCl. The dimers were focused in an electrostatic hexapole field. Using computer simulation, the focusing curve could be fit, assuming contributions from both first and second order Stark effects. The dipole moment, based on simulation, was found to be 1.5 ± 0.1 D. The ability to observe an effective dipole moment in a system where the donor-acceptor tunneling is fast is surprising. It may indicate that the understanding of the interaction of floppy systems with hexapole field is not complete.
UR - http://www.scopus.com/inward/record.url?scp=0030572551&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=0030572551&partnerID=8YFLogxK
M3 - Article
AN - SCOPUS:0030572551
VL - 259
SP - 356
EP - 360
JO - Chemical Physics Letters
JF - Chemical Physics Letters
SN - 0009-2614
IS - 3-4
ER -