Fabrication of a cyanide-bridged coordination polymer electrode for enhanced electrochemical ion storage ability

Daisuke Asakura, Masashi Okubo, Yoshifumi Mizuno, Tetsuichi Kudo, Haoshen Zhou, Kazumichi Ikedo, Takashi Mizokawa, Atsushi Okazawa, Norimichi Kojima

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67 Citations (Scopus)

Abstract

Host frameworks with the ability to store guest ions are very important in a wide range of applications including electrode materials for Li-ion batteries. In this report, we demonstrate that the ion storage ability of the cyanide-bridged coordination polymer (Prussian blue analogue, PBA) can be enhanced by suppressing vacancy formation. K-ions in the vacancy-suppressed PBA framework K 1.72Mn[Mn(CN) 6] 0.93·□ 0.07·0.65H 2O (□: a [Mn(CN) 6] 4- defect) were electrochemically extracted. The open circuit voltages (OCVs) during K-ion extraction exhibited two specific plateaus at 3.0 and 3.7 V vs Li/Li +. Ex situ X-ray diffraction and IR spectroscopy revealed drastic structural and electronic changes during K-ion extraction. Furthermore, after K-ion extraction, the vacancy-suppressed PBA framework was applied to the cathode material for a Li-ion battery. The charge/discharge experiments revealed that the framework can accommodate a large amount of Li-ions.

Original languageEnglish
Pages (from-to)8364-8369
Number of pages6
JournalJournal of Physical Chemistry C
Volume116
Issue number15
DOIs
Publication statusPublished - 2012 Apr 19

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ASJC Scopus subject areas

  • Electronic, Optical and Magnetic Materials
  • Energy(all)
  • Physical and Theoretical Chemistry
  • Surfaces, Coatings and Films

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