Fabrication of function-graded proton exchange membranes by electron beam irradiation for polymer electrolyte fuel cells under nonhumidified condition

Ryota Tsuchida, Atsushi Tsukamoto, Satoshi Hiraiwa, Akihiro Oshima, Masakazu Washio

    Research output: Contribution to journalArticle

    2 Citations (Scopus)

    Abstract

    Function-graded proton exchange membranes (G-PEMs) for polymer electrolyte fuel cells (PEFCs) are fabricated by electron beam (EB) grafting using a heterogeneous energy deposition technique. The fabricated G-PEMs have a water uptake gradient in the direction of the thickness originating from the sulfonic acid group gradient. Normal PEMs (N-PEMs), which have almost no gradient ionic groups in the membrane, are also fabricated to compare with G-PEMs. PEFC operations for comparing the fabricated G-PEMs, normal PEMs (N-PEMs), and Nafion®212 are carried out at 30 C and 60 C with dry H 2/O2 gases. It is expected that the advantages of using dry fuel gases are lower cost and a smaller size system than that is possible with a humid fuel. The fabricated G-PEMs show a higher power density than Nafion®212 and N-PEMs at 30 C, and the deterioration of the performance of fabricated G-PEMs is lower than that of Nafion ®212. These results are thought to be caused by the difference in proton transfer kinetics between the fabricated G-PEMs and those of Nafion ®212. It is therefore considered that G-PEMs not only exhibit higher performance at low temperature under nonhumidified conditions but also cost less than Nafion®212.

    Original languageEnglish
    Pages (from-to)351-358
    Number of pages8
    JournalJournal of Power Sources
    Volume240
    DOIs
    Publication statusPublished - 2013

    Fingerprint

    Electrolytes
    fuel cells
    Protons
    Fuel cells
    Electron beams
    Ion exchange
    Polymers
    Irradiation
    electrolytes
    electron beams
    membranes
    Membranes
    Fabrication
    fabrication
    irradiation
    protons
    polymers
    gradients
    Proton transfer
    Sulfonic Acids

    Keywords

    • Electron beam
    • Fuel cells
    • Function-graded PEMs
    • Polymer electrolyte fuel cell
    • Proton exchange membranes
    • Radiation-grafting

    ASJC Scopus subject areas

    • Electrical and Electronic Engineering
    • Energy Engineering and Power Technology
    • Renewable Energy, Sustainability and the Environment
    • Physical and Theoretical Chemistry

    Cite this

    Fabrication of function-graded proton exchange membranes by electron beam irradiation for polymer electrolyte fuel cells under nonhumidified condition. / Tsuchida, Ryota; Tsukamoto, Atsushi; Hiraiwa, Satoshi; Oshima, Akihiro; Washio, Masakazu.

    In: Journal of Power Sources, Vol. 240, 2013, p. 351-358.

    Research output: Contribution to journalArticle

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    abstract = "Function-graded proton exchange membranes (G-PEMs) for polymer electrolyte fuel cells (PEFCs) are fabricated by electron beam (EB) grafting using a heterogeneous energy deposition technique. The fabricated G-PEMs have a water uptake gradient in the direction of the thickness originating from the sulfonic acid group gradient. Normal PEMs (N-PEMs), which have almost no gradient ionic groups in the membrane, are also fabricated to compare with G-PEMs. PEFC operations for comparing the fabricated G-PEMs, normal PEMs (N-PEMs), and Nafion{\circledR}212 are carried out at 30 C and 60 C with dry H 2/O2 gases. It is expected that the advantages of using dry fuel gases are lower cost and a smaller size system than that is possible with a humid fuel. The fabricated G-PEMs show a higher power density than Nafion{\circledR}212 and N-PEMs at 30 C, and the deterioration of the performance of fabricated G-PEMs is lower than that of Nafion {\circledR}212. These results are thought to be caused by the difference in proton transfer kinetics between the fabricated G-PEMs and those of Nafion {\circledR}212. It is therefore considered that G-PEMs not only exhibit higher performance at low temperature under nonhumidified conditions but also cost less than Nafion{\circledR}212.",
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