Fabrication of mesoporous Pt inside micrometer channels via "solvent-evaporation-mediated direct physical casting"

Yusuke Yamauchi, Toshiyuki Momma, Hiroki Kitoh, Tetsuya Osaka, Kazuyuki Kuroda

Research output: Contribution to journalArticle

26 Citations (Scopus)

Abstract

We have proposed a novel convenient pathway via solvent-evaporation- mediated direct physical casting (SEDPC) for the fabrication of mesoporous metals in a micrometer scale. We have presented the successful deposition of highly ordered mesoporous Pt into micrometer channels prepared by lithography. The direct observation by a high-resolution scanning microscope (HR-SEM) showed the formation of highly ordered 2D-hexagonal (p6mm) mesoporous metals onto such substrates. The cyclic voltammogram of the mesoporous Pt in sulfuric acid revealed a typical feature which can identify the clean Pt surface. Moreover, mesoporous Pt exhibits an effective reduction of dissolved dioxygen molecules. It is proved that mesoporous Pt deposited in a very confined area via the SEDPC method possesses electrocatalytic performance owing to Pt.

Original languageEnglish
Pages (from-to)1364-1370
Number of pages7
JournalElectrochemistry Communications
Volume7
Issue number12
DOIs
Publication statusPublished - 2005 Dec 1

Keywords

  • Electrocatalyst
  • Lithography
  • Mesoporous metal
  • Microchannel
  • Platinum

ASJC Scopus subject areas

  • Electrochemistry

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