Fabrication of Micro-Gap Electrodes for Molecular Electronics

Tomohiko Edura, Jun Mizuno, Ken Tsutsui, Mikiko Saito, Masahide Tbkuda, Harumasa Onozato, Toshiko Koizumi, Yasuo Wada, Masamitsu Haemori, Hideomi Koinuma

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Abstract

Recently, organic molecular electrical devices such as molecular thin film transistors have received considerable attentions as possible candidates for next generation electrical and optical devices. This paper reports fabricating technologies of flat metallic electrodes on insulating substrates with micro-gap separation. The key technologies of fabricating the planar type electrodes are liftoff method by the combination of bi-layer photoresist with overhang profile and electron beam evaporation of thin metal (Ti and Au) films and SiO2-CMP (Chemical Mechanical Polishing) method of CVD (Chemical Vapor Deposition) deposited TEOS (Tetraethoxysilane) - SiO2 layer. The raggedness of the electrode/insulator interface and the electrode surface on the micro-gap electrodes were less than 3 nm. The isolation characteristics of fabricated electrodes were in the order of 1013 ohm at room temperature, which is enough for analyzing electronic properties of organic thin film devices. Finally, pentacene FET characteristics are discussed fabricated on the micro-gap flat electrodes. The mobility of this FET was 0.015cm2/Vs, which was almost on the order of the previous results. These results suggest that high performance organic thin film transistors would be realized on these advanced electrode structures.

Original languageEnglish
Pages (from-to)1213-1218
Number of pages6
JournalIEEJ Transactions on Electronics, Information and Systems
Volume124
Issue number6
DOIs
Publication statusPublished - 2004 Jan

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Keywords

  • CMP
  • flat electrode
  • micro-gap
  • molecular electronics
  • nano-gap

ASJC Scopus subject areas

  • Electrical and Electronic Engineering

Cite this

Edura, T., Mizuno, J., Tsutsui, K., Saito, M., Tbkuda, M., Onozato, H., Koizumi, T., Wada, Y., Haemori, M., & Koinuma, H. (2004). Fabrication of Micro-Gap Electrodes for Molecular Electronics. IEEJ Transactions on Electronics, Information and Systems, 124(6), 1213-1218. https://doi.org/10.1541/ieejeiss.124.1213