Facile catalytic SNAr reaction of nonactivated fluoroarenes with amines using η6-benzene ruthenium(II) complex

Maiko Otsuka, Hiroya Yokoyama, Kohei Endo, Takanori Shibata

Research output: Contribution to journalArticle

14 Citations (Scopus)

Abstract

Catalytic SNAr reaction of fluoroarenes possessing no electron-withdrawing group(s) with cyclic amines was achieved using a readily accessible Ru catalyst, which was prepared from [Ru(benzene)Cl2] 2, AgOTf, and P(p-FC6H4)3. The coexistence of molecular sieves MS4A realized high conversion and various substituted aryl amines were obtained in good to high yields.

Original languageEnglish
Pages (from-to)2601-2606
Number of pages6
JournalSynlett
Issue number17
DOIs
Publication statusPublished - 2010 Oct 25

Keywords

  • SAr reaction
  • amines
  • catalysis
  • fluoroarenes
  • ruthenium

ASJC Scopus subject areas

  • Organic Chemistry

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