Facile reduction of poly(2,5-dialkoxy-p-phenylene ethynylene)s: An efficient route for the synthesis of poly(2,5-dialkoxy-p-xylylene)s

J. Benjamin Beck; Akshay Kokil; Dale Ray; Stuart J. Rowan; Christoph Weder

doi:10.1021/ma011386g

Facile reduction of poly(2,5-dialkoxy-p-phenylene ethynylene)s: An efficient route for the synthesis of poly(2,5-dialkoxy-p-xylylene)s

J. Benjamin Beck, Akshay Kokil, Dale Ray, Stuart J. Rowan, Christoph Weder

Research output: Contribution to journal › Article

25 Citations (Scopus)

Abstract

A study was carried out to show that diimide generated from p-toluenesulfonhydrazide and tripropylamine is a convenient and very effective reagent for the hydrogenation of PPEs under mild and undemanding conditions. In the initial experiments, this protocol was employed to reduce two different PPE derivatives to the corresponding poly(p-xylene)s.

Original language	English
Pages (from-to)	590-593
Number of pages	4
Journal	Macromolecules
Volume	35
Issue number	3
DOIs	https://doi.org/10.1021/ma011386g
Publication status	Published - 2002 Jan 29
Externally published	Yes

Fingerprint

Xylene

Hydrogenation

Derivatives

Experiments

4-toluenesulfonyl hydrazide

4-xylene

tripropylamine

ASJC Scopus subject areas

Materials Chemistry

Cite this

Beck, J. B., Kokil, A., Ray, D., Rowan, S. J., & Weder, C. (2002). Facile reduction of poly(2,5-dialkoxy-p-phenylene ethynylene)s: An efficient route for the synthesis of poly(2,5-dialkoxy-p-xylylene)s. Macromolecules, 35(3), 590-593. https://doi.org/10.1021/ma011386g

Facile reduction of poly(2,5-dialkoxy-p-phenylene ethynylene)s : An efficient route for the synthesis of poly(2,5-dialkoxy-p-xylylene)s. / Beck, J. Benjamin; Kokil, Akshay; Ray, Dale; Rowan, Stuart J.; Weder, Christoph.

In: Macromolecules, Vol. 35, No. 3, 29.01.2002, p. 590-593.

Research output: Contribution to journal › Article

Beck, JB, Kokil, A, Ray, D, Rowan, SJ & Weder, C 2002, 'Facile reduction of poly(2,5-dialkoxy-p-phenylene ethynylene)s: An efficient route for the synthesis of poly(2,5-dialkoxy-p-xylylene)s', Macromolecules, vol. 35, no. 3, pp. 590-593. https://doi.org/10.1021/ma011386g

Beck JB, Kokil A, Ray D, Rowan SJ, Weder C. Facile reduction of poly(2,5-dialkoxy-p-phenylene ethynylene)s: An efficient route for the synthesis of poly(2,5-dialkoxy-p-xylylene)s. Macromolecules. 2002 Jan 29;35(3):590-593. https://doi.org/10.1021/ma011386g

Beck, J. Benjamin ; Kokil, Akshay ; Ray, Dale ; Rowan, Stuart J. ; Weder, Christoph. / Facile reduction of poly(2,5-dialkoxy-p-phenylene ethynylene)s : An efficient route for the synthesis of poly(2,5-dialkoxy-p-xylylene)s. In: Macromolecules. 2002 ; Vol. 35, No. 3. pp. 590-593.

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10.1021/ma011386g