Facile Synthesis of Keto Nitriles by Cu(II)-Promoted Photooxidative Cleavage of Cyclic Olefins

Isao Shimizu, Munetsugu Fujita, Takayuki Nakajima, Tadashi Sato

Research output: Contribution to journalArticle

14 Citations (Scopus)

Abstract

Reaction of trisubstituted cyclic olefins with NaN3 in the presence of Cu(OTf)2 upon irradiation under oxygen gave keto nitriles in good yields. 1,5-Dimethyl-1,5-cyclooctadiene and 1,5,9-trimethyl-1,5,9-cyclododecatriene were converted into the corresponding unsaturated keto nitriles.

Original languageEnglish
Pages (from-to)887-888
Number of pages2
JournalSynlett
Volume1997
Issue number8
Publication statusPublished - 1997

Fingerprint

Cycloparaffins
Nitriles
1,5,9-cyclododecatriene
Sodium Azide
Irradiation
Oxygen

ASJC Scopus subject areas

  • Organic Chemistry

Cite this

Shimizu, I., Fujita, M., Nakajima, T., & Sato, T. (1997). Facile Synthesis of Keto Nitriles by Cu(II)-Promoted Photooxidative Cleavage of Cyclic Olefins. Synlett, 1997(8), 887-888.

Facile Synthesis of Keto Nitriles by Cu(II)-Promoted Photooxidative Cleavage of Cyclic Olefins. / Shimizu, Isao; Fujita, Munetsugu; Nakajima, Takayuki; Sato, Tadashi.

In: Synlett, Vol. 1997, No. 8, 1997, p. 887-888.

Research output: Contribution to journalArticle

Shimizu, I, Fujita, M, Nakajima, T & Sato, T 1997, 'Facile Synthesis of Keto Nitriles by Cu(II)-Promoted Photooxidative Cleavage of Cyclic Olefins', Synlett, vol. 1997, no. 8, pp. 887-888.
Shimizu, Isao ; Fujita, Munetsugu ; Nakajima, Takayuki ; Sato, Tadashi. / Facile Synthesis of Keto Nitriles by Cu(II)-Promoted Photooxidative Cleavage of Cyclic Olefins. In: Synlett. 1997 ; Vol. 1997, No. 8. pp. 887-888.
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