Fluorescent Ferroelectrics of Hydrogen-Bonded Pyrene Derivatives

Hayato Anetai, Yoshifumi Wada, Takashi Takeda, Norihisa Hoshino, Shunsuke Yamamoto, Masaya Mitsuishi, Taishi Takenobu, Tomoyuki Akutagawa

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    Organic materials with diverse molecular designs show multifunctional properties such as coupled ferroelectric, optical, ferromagnetic, and transport properties. We report the design of an alkylamide-substituted pyrene derivative displaying fluorescent ferroelectric properties coupled with electron transport properties. In solution phase, this compound displayed concentration-dependent fluorescence, whereas in xerogels, a fluorescent green organogel (>0.1 mM) and entangled nanofibers were observed. A discotic hexagonal columnar liquid crystalline phase was observed above 295 K due to intermolecular hydrogen bonding and π-stacking interactions. The direction of the hydrogen-bonded chains could be inverted by the application of an external electric field along the π-stacked column, resulting in ferroelectric polarization-electric field (P-E) hysteresis. The local electric field arising from the ferroelectric macrodipole moment arrangement along the π-stacking direction affected the electron transport properties on the π-stack of pyrenes, thus confirming the current-switching phenomena according to P-E hysteresis. We report that multifunctional properties such as ferroelectricity, fluorescence, and electron transport switching were successfully achieved in hydrogen-bonded dynamic π-molecular assemblies. (Graph Presented).

    Original languageEnglish
    Pages (from-to)1813-1818
    Number of pages6
    JournalJournal of Physical Chemistry Letters
    Issue number10
    Publication statusPublished - 2015 May 21

    ASJC Scopus subject areas

    • Materials Science(all)

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    Anetai, H., Wada, Y., Takeda, T., Hoshino, N., Yamamoto, S., Mitsuishi, M., Takenobu, T., & Akutagawa, T. (2015). Fluorescent Ferroelectrics of Hydrogen-Bonded Pyrene Derivatives. Journal of Physical Chemistry Letters, 6(10), 1813-1818. https://doi.org/10.1021/acs.jpclett.5b00703