Formation of a ligand-based mixed-valence cluster triggered by dehydration condensation of semiquinonates with o-phenylenediamines

Ho Chol Chang; Nao Nishida; Susumu Kitagawa

doi:10.1246/cl.2005.402

Formation of a ligand-based mixed-valence cluster triggered by dehydration condensation of semiquinonates with o-phenylenediamines

Ho Chol Chang, Nao Nishida, Susumu Kitagawa^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

9 Citations (Scopus)

Abstract

A tetrameric [Co^II(phenSQ)₂]₄ with homovalent semiquinonates reacts with o-phenylenediamines to give a ligand-based mixed-valence pentanuclear cluster [{Co^II₅(phenSQ) ₄(phen-Cat)₃(THF)₃(H₂O)}·THF] , containing two differently charged ligands, whose formation is triggered by a dehydration condensation reaction between the semiquinonates and o-phenylenediamines.

Original language	English
Pages (from-to)	402-403
Number of pages	2
Journal	Chemistry Letters
Volume	34
Issue number	3
DOIs	https://doi.org/10.1246/cl.2005.402
Publication status	Published - 2005 Mar 5
Externally published	Yes

ASJC Scopus subject areas

Chemistry(all)

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title = "Formation of a ligand-based mixed-valence cluster triggered by dehydration condensation of semiquinonates with o-phenylenediamines",

abstract = "A tetrameric [CoII(phenSQ)2]4 with homovalent semiquinonates reacts with o-phenylenediamines to give a ligand-based mixed-valence pentanuclear cluster [{CoII5(phenSQ) 4(phen-Cat)3(THF)3(H2O)}·THF] , containing two differently charged ligands, whose formation is triggered by a dehydration condensation reaction between the semiquinonates and o-phenylenediamines.",

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year = "2005",

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AU - Chang, Ho Chol

AU - Nishida, Nao

AU - Kitagawa, Susumu

PY - 2005/3/5

Y1 - 2005/3/5

N2 - A tetrameric [CoII(phenSQ)2]4 with homovalent semiquinonates reacts with o-phenylenediamines to give a ligand-based mixed-valence pentanuclear cluster [{CoII5(phenSQ) 4(phen-Cat)3(THF)3(H2O)}·THF] , containing two differently charged ligands, whose formation is triggered by a dehydration condensation reaction between the semiquinonates and o-phenylenediamines.

AB - A tetrameric [CoII(phenSQ)2]4 with homovalent semiquinonates reacts with o-phenylenediamines to give a ligand-based mixed-valence pentanuclear cluster [{CoII5(phenSQ) 4(phen-Cat)3(THF)3(H2O)}·THF] , containing two differently charged ligands, whose formation is triggered by a dehydration condensation reaction between the semiquinonates and o-phenylenediamines.

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ER -

Formation of a ligand-based mixed-valence cluster triggered by dehydration condensation of semiquinonates with o-phenylenediamines

Abstract

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