Formation of a new crystalline silicate structure by grafting dialkoxysilyl groups on layered octosilicate

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53 Citations (Scopus)

Abstract

Dialkoxydichlorosilanes ((RO)2SiCl2, R = alkyl) react almost completely with interlayer silanol groups in a layered silicate octosilicate to create a new crystalline silicate structure consisting of new five-membered rings arranged regularly on both sides of the silicate layers. The introduction of dialkoxysilyl groups to the interlamellar region of layered silicates with regular reaction sites provides a new methodology for the design and construction of novel crystalline silicate frameworks by a soft chemical route.

Original languageEnglish
Pages (from-to)12082-12083
Number of pages2
JournalJournal of the American Chemical Society
Volume124
Issue number41
DOIs
Publication statusPublished - 2002 Oct 16

ASJC Scopus subject areas

  • Catalysis
  • Chemistry(all)
  • Biochemistry
  • Colloid and Surface Chemistry

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