Formation of a new crystalline silicate structure by grafting dialkoxysilyl groups on layered octosilicate

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    53 Citations (Scopus)

    Abstract

    Dialkoxydichlorosilanes ((RO)2SiCl2, R = alkyl) react almost completely with interlayer silanol groups in a layered silicate octosilicate to create a new crystalline silicate structure consisting of new five-membered rings arranged regularly on both sides of the silicate layers. The introduction of dialkoxysilyl groups to the interlamellar region of layered silicates with regular reaction sites provides a new methodology for the design and construction of novel crystalline silicate frameworks by a soft chemical route.

    Original languageEnglish
    Pages (from-to)12082-12083
    Number of pages2
    JournalJournal of the American Chemical Society
    Volume124
    Issue number41
    DOIs
    Publication statusPublished - 2002 Oct 16

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    Silicates
    Crystalline materials
    octosilicate

    ASJC Scopus subject areas

    • Chemistry(all)

    Cite this

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    abstract = "Dialkoxydichlorosilanes ((RO)2SiCl2, R = alkyl) react almost completely with interlayer silanol groups in a layered silicate octosilicate to create a new crystalline silicate structure consisting of new five-membered rings arranged regularly on both sides of the silicate layers. The introduction of dialkoxysilyl groups to the interlamellar region of layered silicates with regular reaction sites provides a new methodology for the design and construction of novel crystalline silicate frameworks by a soft chemical route.",
    author = "Dai Mochizuki and Atsushi Shimojima and Kazuyuki Kuroda",
    year = "2002",
    month = "10",
    day = "16",
    doi = "10.1021/ja027512t",
    language = "English",
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    pages = "12082--12083",
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    T1 - Formation of a new crystalline silicate structure by grafting dialkoxysilyl groups on layered octosilicate

    AU - Mochizuki, Dai

    AU - Shimojima, Atsushi

    AU - Kuroda, Kazuyuki

    PY - 2002/10/16

    Y1 - 2002/10/16

    N2 - Dialkoxydichlorosilanes ((RO)2SiCl2, R = alkyl) react almost completely with interlayer silanol groups in a layered silicate octosilicate to create a new crystalline silicate structure consisting of new five-membered rings arranged regularly on both sides of the silicate layers. The introduction of dialkoxysilyl groups to the interlamellar region of layered silicates with regular reaction sites provides a new methodology for the design and construction of novel crystalline silicate frameworks by a soft chemical route.

    AB - Dialkoxydichlorosilanes ((RO)2SiCl2, R = alkyl) react almost completely with interlayer silanol groups in a layered silicate octosilicate to create a new crystalline silicate structure consisting of new five-membered rings arranged regularly on both sides of the silicate layers. The introduction of dialkoxysilyl groups to the interlamellar region of layered silicates with regular reaction sites provides a new methodology for the design and construction of novel crystalline silicate frameworks by a soft chemical route.

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