Formation of a new crystalline silicate structure by grafting dialkoxysilyl groups on layered octosilicate

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    Abstract

    Dialkoxydichlorosilanes ((RO)2SiCl2, R = alkyl) react almost completely with interlayer silanol groups in a layered silicate octosilicate to create a new crystalline silicate structure consisting of new five-membered rings arranged regularly on both sides of the silicate layers. The introduction of dialkoxysilyl groups to the interlamellar region of layered silicates with regular reaction sites provides a new methodology for the design and construction of novel crystalline silicate frameworks by a soft chemical route.

    Original languageEnglish
    Pages (from-to)12082-12083
    Number of pages2
    JournalJournal of the American Chemical Society
    Volume124
    Issue number41
    DOIs
    Publication statusPublished - 2002 Oct 16

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    ASJC Scopus subject areas

    • Chemistry(all)

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