Formation of a palladalactone complex by C-O bond cleavage of diketene promoted by a zerovalent palladium complex

Ryuki Kakino, Kazuhiro Nagayama, Yoshihito Kayaki, Isao Shimizu, Akio Yamamoto

Research output: Contribution to journalArticle

17 Citations (Scopus)

Abstract

The reaction of diketene with [Pd(PMe3)2(styrene)] 1 at room temperature gave [Pd(OCOCH2C=CH2)(PMe,3)2] 2 through cleavage of the C-O bond adjacent to the carbon bearing the exomethylene group. The structure of 2 was fully established by spectroscopic means, elemental analysis and single-crystal X-ray analysis. The reactivity of 2 has been investigated.

Original languageEnglish
Pages (from-to)685-686
Number of pages2
JournalChemistry Letters
Issue number7
Publication statusPublished - 1999

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Bearings (structural)
Styrene
X ray analysis
Palladium
Carbon
Single crystals
Chemical analysis
Temperature
diketene

ASJC Scopus subject areas

  • Chemistry(all)

Cite this

Kakino, R., Nagayama, K., Kayaki, Y., Shimizu, I., & Yamamoto, A. (1999). Formation of a palladalactone complex by C-O bond cleavage of diketene promoted by a zerovalent palladium complex. Chemistry Letters, (7), 685-686.

Formation of a palladalactone complex by C-O bond cleavage of diketene promoted by a zerovalent palladium complex. / Kakino, Ryuki; Nagayama, Kazuhiro; Kayaki, Yoshihito; Shimizu, Isao; Yamamoto, Akio.

In: Chemistry Letters, No. 7, 1999, p. 685-686.

Research output: Contribution to journalArticle

Kakino, R, Nagayama, K, Kayaki, Y, Shimizu, I & Yamamoto, A 1999, 'Formation of a palladalactone complex by C-O bond cleavage of diketene promoted by a zerovalent palladium complex', Chemistry Letters, no. 7, pp. 685-686.
Kakino, Ryuki ; Nagayama, Kazuhiro ; Kayaki, Yoshihito ; Shimizu, Isao ; Yamamoto, Akio. / Formation of a palladalactone complex by C-O bond cleavage of diketene promoted by a zerovalent palladium complex. In: Chemistry Letters. 1999 ; No. 7. pp. 685-686.
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