FORMATION OF BORON NITRIDE AND BORON CARBIDE BY PYROLYSIS OF CONDENSATION PRODUCTS OF BORIC ACID AND ETHANOLAMINES.

Hiroaki Wada; Kazuaki Nojima; Kazuyuki Kuroda; Chuzo Kato

FORMATION OF BORON NITRIDE AND BORON CARBIDE BY PYROLYSIS OF CONDENSATION PRODUCTS OF BORIC ACID AND ETHANOLAMINES.

Hiroaki Wada, Kazuaki Nojima, Kazuyuki Kuroda, Chuzo Kato

School of Advanced Science and Engineering

Research output: Contribution to journal › Article › peer-review

5 Citations (Scopus)

Abstract

Boron nitride was from boric acid-diethanolamine or -triethanolamine condensation products by their pyrolysis in a nitrogen flow. The condensation products obtained from boric acid-diethanolamine system (molar ratio 1:1 and 2:3) were glassy solids and had a polymeric structure containing the B-O-C bond. Monomeric triethanolamine borate, which contained both B-O-C and coordinate B-N bonds, was formed from boric acid-triethanolamine system. Pyrolysis of these condensation products in N//2 flow at 1400 degree C yielded boron nitride. A small amount of B//4C was also formed, depending on the molar ratio or on the carbon content of the condensation products.

Original language	English
Pages (from-to)	130-134
Number of pages	5
Journal	Yogyo Kyokai Shi/Journal of the Ceramic Society of Japan
Volume	95
Issue number	1
Publication status	Published - 1987 Jan 1

ASJC Scopus subject areas

Engineering(all)

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title = "FORMATION OF BORON NITRIDE AND BORON CARBIDE BY PYROLYSIS OF CONDENSATION PRODUCTS OF BORIC ACID AND ETHANOLAMINES.",

abstract = "Boron nitride was from boric acid-diethanolamine or -triethanolamine condensation products by their pyrolysis in a nitrogen flow. The condensation products obtained from boric acid-diethanolamine system (molar ratio 1:1 and 2:3) were glassy solids and had a polymeric structure containing the B-O-C bond. Monomeric triethanolamine borate, which contained both B-O-C and coordinate B-N bonds, was formed from boric acid-triethanolamine system. Pyrolysis of these condensation products in N//2 flow at 1400 degree C yielded boron nitride. A small amount of B//4C was also formed, depending on the molar ratio or on the carbon content of the condensation products.",

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year = "1987",

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T1 - FORMATION OF BORON NITRIDE AND BORON CARBIDE BY PYROLYSIS OF CONDENSATION PRODUCTS OF BORIC ACID AND ETHANOLAMINES.

AU - Wada, Hiroaki

AU - Nojima, Kazuaki

AU - Kuroda, Kazuyuki

AU - Kato, Chuzo

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N2 - Boron nitride was from boric acid-diethanolamine or -triethanolamine condensation products by their pyrolysis in a nitrogen flow. The condensation products obtained from boric acid-diethanolamine system (molar ratio 1:1 and 2:3) were glassy solids and had a polymeric structure containing the B-O-C bond. Monomeric triethanolamine borate, which contained both B-O-C and coordinate B-N bonds, was formed from boric acid-triethanolamine system. Pyrolysis of these condensation products in N//2 flow at 1400 degree C yielded boron nitride. A small amount of B//4C was also formed, depending on the molar ratio or on the carbon content of the condensation products.

AB - Boron nitride was from boric acid-diethanolamine or -triethanolamine condensation products by their pyrolysis in a nitrogen flow. The condensation products obtained from boric acid-diethanolamine system (molar ratio 1:1 and 2:3) were glassy solids and had a polymeric structure containing the B-O-C bond. Monomeric triethanolamine borate, which contained both B-O-C and coordinate B-N bonds, was formed from boric acid-triethanolamine system. Pyrolysis of these condensation products in N//2 flow at 1400 degree C yielded boron nitride. A small amount of B//4C was also formed, depending on the molar ratio or on the carbon content of the condensation products.

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