Formation of two- and three-dimensional hybrid mesostructures from branched siloxane molecules

Shigeru Sakamoto; Atsushi Shimojima; Keiichi Miyasaka; Juanfang Ruan; Osamu Terasaki; Kazuyuki Kuroda

doi:10.1021/ja903176k

Formation of two- and three-dimensional hybrid mesostructures from branched siloxane molecules

Shigeru Sakamoto, Atsushi Shimojima, Keiichi Miyasaka, Juanfang Ruan, Osamu Terasaki, Kazuyuki Kuroda^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

38 Citations (Scopus)

Abstract

(Chemical Equation Presented) We report the design of a new precursor having three branching disiloxane units capable of forming 3D mesostructures with a cubic Pm-3n and its orthorhombic and tetragonal variants Cmmm and P4 ₂/mnm, in addition to a conventional 2D hexagonal (p6mm) mesostructure, thus creating a novel research area of mesostructural design in silica-organic nanohybrid materials.

Original language	English
Pages (from-to)	9634-9635
Number of pages	2
Journal	Journal of the American Chemical Society
Volume	131
Issue number	28
DOIs	https://doi.org/10.1021/ja903176k
Publication status	Published - 2009 Jul 22
Externally published	Yes

ASJC Scopus subject areas

Catalysis
Chemistry(all)
Biochemistry
Colloid and Surface Chemistry

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abstract = "(Chemical Equation Presented) We report the design of a new precursor having three branching disiloxane units capable of forming 3D mesostructures with a cubic Pm-3n and its orthorhombic and tetragonal variants Cmmm and P4 2/mnm, in addition to a conventional 2D hexagonal (p6mm) mesostructure, thus creating a novel research area of mesostructural design in silica-organic nanohybrid materials.",

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AU - Sakamoto, Shigeru

AU - Shimojima, Atsushi

AU - Miyasaka, Keiichi

AU - Ruan, Juanfang

AU - Terasaki, Osamu

AU - Kuroda, Kazuyuki

PY - 2009/7/22

Y1 - 2009/7/22

N2 - (Chemical Equation Presented) We report the design of a new precursor having three branching disiloxane units capable of forming 3D mesostructures with a cubic Pm-3n and its orthorhombic and tetragonal variants Cmmm and P4 2/mnm, in addition to a conventional 2D hexagonal (p6mm) mesostructure, thus creating a novel research area of mesostructural design in silica-organic nanohybrid materials.

AB - (Chemical Equation Presented) We report the design of a new precursor having three branching disiloxane units capable of forming 3D mesostructures with a cubic Pm-3n and its orthorhombic and tetragonal variants Cmmm and P4 2/mnm, in addition to a conventional 2D hexagonal (p6mm) mesostructure, thus creating a novel research area of mesostructural design in silica-organic nanohybrid materials.

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Formation of two- and three-dimensional hybrid mesostructures from branched siloxane molecules

Abstract

ASJC Scopus subject areas

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