Four-electron reduction of dioxygen catalyzed by a decavanadium complex

Eniya Listiani Dewi, Kenichi Oyaizu, Eishun Tsuchida

    Research output: Contribution to journalArticle

    9 Citations (Scopus)

    Abstract

    The electroreduction of O2 in acidic aqueous solutions at an electrode modified with a decavanadium cluster [(V=O)102-O)93-O) 3(C5H7O2)6] (1) revealed that it produces H2O with four electrons per O2 molecule near 0.5 V versus SCE. The usefulness of the complex as a reduction catalyst of O2 with a high selectivity was demonstrated.

    Original languageEnglish
    Pages (from-to)316-318
    Number of pages3
    JournalInorganica Chimica Acta
    Volume342
    DOIs
    Publication statusPublished - 2003 Jan 10

    Fingerprint

    Catalyst selectivity
    Electrodes
    selectivity
    Electrons
    Oxygen
    aqueous solutions
    catalysts
    Catalysts
    Molecules
    electrodes
    molecules
    electrons

    Keywords

    • Decavanadium
    • Dioxygen
    • Electrochemistry
    • Four-electron reduction

    ASJC Scopus subject areas

    • Biochemistry
    • Inorganic Chemistry
    • Physical and Theoretical Chemistry
    • Materials Chemistry

    Cite this

    Four-electron reduction of dioxygen catalyzed by a decavanadium complex. / Dewi, Eniya Listiani; Oyaizu, Kenichi; Tsuchida, Eishun.

    In: Inorganica Chimica Acta, Vol. 342, 10.01.2003, p. 316-318.

    Research output: Contribution to journalArticle

    Dewi, Eniya Listiani ; Oyaizu, Kenichi ; Tsuchida, Eishun. / Four-electron reduction of dioxygen catalyzed by a decavanadium complex. In: Inorganica Chimica Acta. 2003 ; Vol. 342. pp. 316-318.
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