Four-electron reduction of dioxygen catalyzed by a decavanadium complex

Eniya Listiani Dewi, Kenichi Oyaizu, Eishun Tsuchida

Research output: Contribution to journalArticle

9 Citations (Scopus)

Abstract

The electroreduction of O2 in acidic aqueous solutions at an electrode modified with a decavanadium cluster [(V=O)102-O)93-O) 3(C5H7O2)6] (1) revealed that it produces H2O with four electrons per O2 molecule near 0.5 V versus SCE. The usefulness of the complex as a reduction catalyst of O2 with a high selectivity was demonstrated.

Original languageEnglish
Pages (from-to)316-318
Number of pages3
JournalInorganica Chimica Acta
Volume342
DOIs
Publication statusPublished - 2003 Jan 10

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Keywords

  • Decavanadium
  • Dioxygen
  • Electrochemistry
  • Four-electron reduction

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Inorganic Chemistry
  • Materials Chemistry

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