Free-energy model of phase inversion dynamics in binary phase separation

Yoshihide Kubo, Shinpei Tanaka, Yoshihiro Yamazaki

Research output: Contribution to journalArticle

Abstract

We propose here an alternative way to understand the characteristic pattern formation found in the so-called viscoelastic phase separations. Since the viscoelastic phase separations have been observed in systems with strong viscoelastic nature such as polymer solutions, numerical modelings for them have been conducted so far by introducing dynamic properties such as concentration-dependent mobility or elastic relaxation moduli to a usual scheme of phase separations. In contrast to these approaches, we propose the introduction of a small change, a bump, in the local free-energy function, keeping a parameter representing dynamic properties constant. We show that the bump in the local free-energy function successfully induces desired pattern formations in a controlled way, while it does not change equilibrium states. The mechanisms by which this free-energy approach reproduces experimentally observed pattern formations are discussed.

Original languageEnglish
Article number022137
JournalPhysical Review E
Volume100
Issue number2
DOIs
Publication statusPublished - 2019 Aug 26

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Energy Model
Phase Separation
Pattern Formation
Free Energy
Inversion
free energy
Dynamic Properties
inversions
Binary
Energy Function
dynamic characteristics
Polymer Solution
Numerical Modeling
Equilibrium State
Modulus
Dependent
Alternatives
polymers

ASJC Scopus subject areas

  • Statistical and Nonlinear Physics
  • Statistics and Probability
  • Condensed Matter Physics

Cite this

Free-energy model of phase inversion dynamics in binary phase separation. / Kubo, Yoshihide; Tanaka, Shinpei; Yamazaki, Yoshihiro.

In: Physical Review E, Vol. 100, No. 2, 022137, 26.08.2019.

Research output: Contribution to journalArticle

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