Half-way coordination state of a butadienyl group on ruthenium. η3-Allylic bonding with η1-character or vice versa

Yasuo Wakatsuki; Hiroshi Yamazaki; Yooichiroh Maruyama; Isao Shimizu

doi:10.1016/0022-328X(92)83276-N

Half-way coordination state of a butadienyl group on ruthenium. η³-Allylic bonding with η¹-character or vice versa

Yasuo Wakatsuki, Hiroshi Yamazaki, Yooichiroh Maruyama, Isao Shimizu

Waseda University

Research output: Contribution to journal › Article › peer-review

21 Citations (Scopus)

Abstract

The butadienyl complexes formed by the reaction of trans-(R¹)CHCHCCR² (R¹, R² SiMe₃, ^tBu, Me, Et) with RuCl(CO)H(PPh₃)₃ exhibit unique structures: instead of taking the 18-electron configuration of the metal by conventional η³-coordination of the butadienyl ligand, they shift significantly to the 16-electron η¹-coordination state.

Original language	English
Journal	Journal of Organometallic Chemistry
Volume	430
Issue number	3
DOIs	https://doi.org/10.1016/0022-328X(92)83276-N
Publication status	Published - 1992 Jun 16

ASJC Scopus subject areas

Biochemistry
Chemical Engineering (miscellaneous)
Inorganic Chemistry
Organic Chemistry
Physical and Theoretical Chemistry
Materials Science (miscellaneous)
Materials Chemistry

Access to Document

10.1016/0022-328X(92)83276-N

Fingerprint Dive into the research topics of 'Half-way coordination state of a butadienyl group on ruthenium. η<sup>3</sup>-Allylic bonding with η<sup>1</sup>-character or vice versa'. Together they form a unique fingerprint.

Cite this

@article{e8e09647d1cb4a7285be33591e564ef0,

title = "Half-way coordination state of a butadienyl group on ruthenium. η3-Allylic bonding with η1-character or vice versa",

abstract = "The butadienyl complexes formed by the reaction of trans-(R1)CHCHCCR2 (R1, R2 SiMe3, tBu, Me, Et) with RuCl(CO)H(PPh3)3 exhibit unique structures: instead of taking the 18-electron configuration of the metal by conventional η3-coordination of the butadienyl ligand, they shift significantly to the 16-electron η1-coordination state.",

author = "Yasuo Wakatsuki and Hiroshi Yamazaki and Yooichiroh Maruyama and Isao Shimizu",

year = "1992",

month = jun,

day = "16",

doi = "10.1016/0022-328X(92)83276-N",

language = "English",

volume = "430",

journal = "Journal of Organometallic Chemistry",

issn = "0022-328X",

publisher = "Elsevier",

number = "3",

}

TY - JOUR

T1 - Half-way coordination state of a butadienyl group on ruthenium. η3-Allylic bonding with η1-character or vice versa

AU - Wakatsuki, Yasuo

AU - Yamazaki, Hiroshi

AU - Maruyama, Yooichiroh

AU - Shimizu, Isao

PY - 1992/6/16

Y1 - 1992/6/16

N2 - The butadienyl complexes formed by the reaction of trans-(R1)CHCHCCR2 (R1, R2 SiMe3, tBu, Me, Et) with RuCl(CO)H(PPh3)3 exhibit unique structures: instead of taking the 18-electron configuration of the metal by conventional η3-coordination of the butadienyl ligand, they shift significantly to the 16-electron η1-coordination state.

AB - The butadienyl complexes formed by the reaction of trans-(R1)CHCHCCR2 (R1, R2 SiMe3, tBu, Me, Et) with RuCl(CO)H(PPh3)3 exhibit unique structures: instead of taking the 18-electron configuration of the metal by conventional η3-coordination of the butadienyl ligand, they shift significantly to the 16-electron η1-coordination state.

UR - http://www.scopus.com/inward/record.url?scp=0002466929&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=0002466929&partnerID=8YFLogxK

U2 - 10.1016/0022-328X(92)83276-N

DO - 10.1016/0022-328X(92)83276-N

M3 - Article

AN - SCOPUS:0002466929

VL - 430

JO - Journal of Organometallic Chemistry

JF - Journal of Organometallic Chemistry

SN - 0022-328X

IS - 3