Half-way coordination state of a butadienyl group on ruthenium. η3-Allylic bonding with η1-character or vice versa

Yasuo Wakatsuki; Hiroshi Yamazaki; Yooichiroh Maruyama; Isao Shimizu

doi:10.1016/0022-328X(92)83276-N

Half-way coordination state of a butadienyl group on ruthenium. η³-Allylic bonding with η¹-character or vice versa

Yasuo Wakatsuki, Hiroshi Yamazaki, Yooichiroh Maruyama, Isao Shimizu

Waseda University

Research output: Contribution to journal › Article

21 Citations (Scopus)

Abstract

The butadienyl complexes formed by the reaction of trans-(R¹)CHCHCCR² (R¹, R² SiMe₃, ^tBu, Me, Et) with RuCl(CO)H(PPh₃)₃ exhibit unique structures: instead of taking the 18-electron configuration of the metal by conventional η³-coordination of the butadienyl ligand, they shift significantly to the 16-electron η¹-coordination state.

Original language	English
Journal	Journal of Organometallic Chemistry
Volume	430
Issue number	3
DOIs	https://doi.org/10.1016/0022-328X(92)83276-N
Publication status	Published - 1992 Jun 16

Fingerprint

ASJC Scopus subject areas

Biochemistry
Chemical Engineering (miscellaneous)
Inorganic Chemistry
Organic Chemistry
Physical and Theoretical Chemistry
Materials Science (miscellaneous)
Materials Chemistry

Cite this

Wakatsuki, Y., Yamazaki, H., Maruyama, Y., & Shimizu, I. (1992). Half-way coordination state of a butadienyl group on ruthenium. η³-Allylic bonding with η¹-character or vice versa. Journal of Organometallic Chemistry, 430(3). https://doi.org/10.1016/0022-328X(92)83276-N

@article{e8e09647d1cb4a7285be33591e564ef0,

title = "Half-way coordination state of a butadienyl group on ruthenium. η3-Allylic bonding with η1-character or vice versa",

abstract = "The butadienyl complexes formed by the reaction of trans-(R1)CHCHCCR2 (R1, R2 SiMe3, tBu, Me, Et) with RuCl(CO)H(PPh3)3 exhibit unique structures: instead of taking the 18-electron configuration of the metal by conventional η3-coordination of the butadienyl ligand, they shift significantly to the 16-electron η1-coordination state.",

author = "Yasuo Wakatsuki and Hiroshi Yamazaki and Yooichiroh Maruyama and Isao Shimizu",

year = "1992",

month = jun

day = "16",

doi = "10.1016/0022-328X(92)83276-N",

language = "English",

volume = "430",

journal = "Journal of Organometallic Chemistry",

issn = "0022-328X",

publisher = "Elsevier",

number = "3",

}

TY - JOUR

T1 - Half-way coordination state of a butadienyl group on ruthenium. η3-Allylic bonding with η1-character or vice versa

AU - Wakatsuki, Yasuo

AU - Yamazaki, Hiroshi

AU - Maruyama, Yooichiroh

AU - Shimizu, Isao

PY - 1992/6/16

Y1 - 1992/6/16

N2 - The butadienyl complexes formed by the reaction of trans-(R1)CHCHCCR2 (R1, R2 SiMe3, tBu, Me, Et) with RuCl(CO)H(PPh3)3 exhibit unique structures: instead of taking the 18-electron configuration of the metal by conventional η3-coordination of the butadienyl ligand, they shift significantly to the 16-electron η1-coordination state.

AB - The butadienyl complexes formed by the reaction of trans-(R1)CHCHCCR2 (R1, R2 SiMe3, tBu, Me, Et) with RuCl(CO)H(PPh3)3 exhibit unique structures: instead of taking the 18-electron configuration of the metal by conventional η3-coordination of the butadienyl ligand, they shift significantly to the 16-electron η1-coordination state.

UR - http://www.scopus.com/inward/record.url?scp=0002466929&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=0002466929&partnerID=8YFLogxK

U2 - 10.1016/0022-328X(92)83276-N

DO - 10.1016/0022-328X(92)83276-N

M3 - Article

AN - SCOPUS:0002466929

VL - 430

JO - Journal of Organometallic Chemistry

JF - Journal of Organometallic Chemistry

SN - 0022-328X

IS - 3

ER -

Access to Document

10.1016/0022-328X(92)83276-N