Half-way coordination state of a butadienyl group on ruthenium. η3-Allylic bonding with η1-character or vice versa

Yasuo Wakatsuki; Hiroshi Yamazaki; Yooichiroh Maruyama; Isao Shimizu

doi:10.1016/0022-328X(92)83276-N

Half-way coordination state of a butadienyl group on ruthenium. η³-Allylic bonding with η¹-character or vice versa

Yasuo Wakatsuki, Hiroshi Yamazaki, Yooichiroh Maruyama, Isao Shimizu

Waseda University

Research output: Contribution to journal › Article

21 Citations (Scopus)

Abstract

The butadienyl complexes formed by the reaction of trans-(R¹)CHCHCCR² (R¹, R² SiMe₃, ^tBu, Me, Et) with RuCl(CO)H(PPh₃)₃ exhibit unique structures: instead of taking the 18-electron configuration of the metal by conventional η³-coordination of the butadienyl ligand, they shift significantly to the 16-electron η¹-coordination state.

Original language	English
Journal	Journal of Organometallic Chemistry
Volume	430
Issue number	3
DOIs	https://doi.org/10.1016/0022-328X(92)83276-N
Publication status	Published - 1992 Jun 16

ASJC Scopus subject areas

Biochemistry
Chemical Engineering (miscellaneous)
Inorganic Chemistry
Organic Chemistry
Physical and Theoretical Chemistry
Materials Science (miscellaneous)
Materials Chemistry

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10.1016/0022-328X(92)83276-N

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Wakatsuki, Y., Yamazaki, H., Maruyama, Y., & Shimizu, I. (1992). Half-way coordination state of a butadienyl group on ruthenium. η³-Allylic bonding with η¹-character or vice versa. Journal of Organometallic Chemistry, 430(3). https://doi.org/10.1016/0022-328X(92)83276-N

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