Half-way coordination state of a butadienyl group on ruthenium. η3-Allylic bonding with η1-character or vice versa

Yasuo Wakatsuki, Hiroshi Yamazaki, Yooichiroh Maruyama, Isao Shimizu

Research output: Contribution to journalArticle

21 Citations (Scopus)

Abstract

The butadienyl complexes formed by the reaction of trans-(R1)CHCHCCR2 (R1, R2 SiMe3, tBu, Me, Et) with RuCl(CO)H(PPh3)3 exhibit unique structures: instead of taking the 18-electron configuration of the metal by conventional η3-coordination of the butadienyl ligand, they shift significantly to the 16-electron η1-coordination state.

Original languageEnglish
JournalJournal of Organometallic Chemistry
Volume430
Issue number3
DOIs
Publication statusPublished - 1992 Jun 16

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Ruthenium
ruthenium
Electrons
Carbon Monoxide
electrons
Metals
Ligands
ligands
shift
configurations
metals

ASJC Scopus subject areas

  • Biochemistry
  • Chemical Engineering (miscellaneous)
  • Inorganic Chemistry
  • Organic Chemistry
  • Physical and Theoretical Chemistry
  • Materials Science (miscellaneous)
  • Materials Chemistry

Cite this

Half-way coordination state of a butadienyl group on ruthenium. η3-Allylic bonding with η1-character or vice versa. / Wakatsuki, Yasuo; Yamazaki, Hiroshi; Maruyama, Yooichiroh; Shimizu, Isao.

In: Journal of Organometallic Chemistry, Vol. 430, No. 3, 16.06.1992.

Research output: Contribution to journalArticle

Wakatsuki, Yasuo ; Yamazaki, Hiroshi ; Maruyama, Yooichiroh ; Shimizu, Isao. / Half-way coordination state of a butadienyl group on ruthenium. η3-Allylic bonding with η1-character or vice versa. In: Journal of Organometallic Chemistry. 1992 ; Vol. 430, No. 3.
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