Abstract
The butadienyl complexes formed by the reaction of trans-(R1)CHCHCCR2 (R1, R2 SiMe3, tBu, Me, Et) with RuCl(CO)H(PPh3)3 exhibit unique structures: instead of taking the 18-electron configuration of the metal by conventional η3-coordination of the butadienyl ligand, they shift significantly to the 16-electron η1-coordination state.
Original language | English |
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Journal | Journal of Organometallic Chemistry |
Volume | 430 |
Issue number | 3 |
DOIs | |
Publication status | Published - 1992 Jun 16 |
ASJC Scopus subject areas
- Biochemistry
- Chemical Engineering (miscellaneous)
- Inorganic Chemistry
- Organic Chemistry
- Physical and Theoretical Chemistry
- Materials Science (miscellaneous)
- Materials Chemistry