Heck-type benzylation of olefins with benzyl trifluoroacetates

Hirohisa Narahashi, Akio Yamamoto, Isao Shimizu

Research output: Contribution to journalArticle

47 Citations (Scopus)

Abstract

A new synthetic method for 1-aryl-2-alkenes from 1-olefins by benzylation treating with benzyl trifluoroacetates using palladium-catalyst is developed on the basis of oxidative addition of benzyl carboxylates to Pd(0) complexes to give benzyl(carboxylato)palladium(II) complexes with cleavage of benzyl-oxygen bond.

Original languageEnglish
Pages (from-to)348-349
Number of pages2
JournalChemistry Letters
Volume33
Issue number3
DOIs
Publication statusPublished - 2004 Mar

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Trifluoroacetic Acid
Palladium
Alkenes
Oxygen
Catalysts

ASJC Scopus subject areas

  • Chemistry(all)

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Heck-type benzylation of olefins with benzyl trifluoroacetates. / Narahashi, Hirohisa; Yamamoto, Akio; Shimizu, Isao.

In: Chemistry Letters, Vol. 33, No. 3, 03.2004, p. 348-349.

Research output: Contribution to journalArticle

Narahashi, H, Yamamoto, A & Shimizu, I 2004, 'Heck-type benzylation of olefins with benzyl trifluoroacetates', Chemistry Letters, vol. 33, no. 3, pp. 348-349. https://doi.org/10.1246/cl.2004.348
Narahashi, Hirohisa ; Yamamoto, Akio ; Shimizu, Isao. / Heck-type benzylation of olefins with benzyl trifluoroacetates. In: Chemistry Letters. 2004 ; Vol. 33, No. 3. pp. 348-349.
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